دورية أكاديمية
Carbonization and oxidation of metal–organic frameworks based on 1,4-naphthalene dicarboxylates
العنوان: | Carbonization and oxidation of metal–organic frameworks based on 1,4-naphthalene dicarboxylates |
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المؤلفون: | Jiun-Jen Chen, Ya-Ting Chen, Duraisamy Senthil Raja, Yu-Hao Kang, Pen-Chang Tseng, Chia-Her Lin |
المصدر: | Science and Technology of Advanced Materials, Vol 16, Iss 5 (2015) |
بيانات النشر: | Taylor & Francis Group, 2015. |
سنة النشر: | 2015 |
المجموعة: | LCC:Materials of engineering and construction. Mechanics of materials LCC:Biotechnology |
مصطلحات موضوعية: | nanoporous carbon, metal oxide nanoparticle, metal–organic frameworks, Materials of engineering and construction. Mechanics of materials, TA401-492, Biotechnology, TP248.13-248.65 |
الوصف: | Three new isostructural metal–organic frameworks (MOFs), [V(OH)(NDC)] (1), [Cr(OH)(NDC)] (2), and [Ga(OH)(NDC)] (3) have been synthesized hydrothermally using 1,4-naphthalene dicarboxylate (NDC) as the linker. These MOFs (1, 2 and 3) have been used as a template for the synthesis of metal-oxide-inserted nanoporous carbon materials. The newly synthesized MOFs and the resulting porous carbon hybrid functional materials have been characterized using powder x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy dispersive x-ray spectroscopic analysis. Results show that compounds 2 and 3 form their respective metal oxide nanoparticles on the surface of the carbon materials during carbonization at 800 °C. The gas sorption properties of the new MOFs and their corresponding carbon frameworks have been reported. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 1468-6996 1878-5514 |
العلاقة: | https://doaj.org/toc/1468-6996Test; https://doaj.org/toc/1878-5514Test |
DOI: | 10.1088/1468-6996/16/5/054203 |
الوصول الحر: | https://doaj.org/article/96c968ae5e4747d1acc5034bb5e47ad3Test |
رقم الانضمام: | edsdoj.96c968ae5e4747d1acc5034bb5e47ad3 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 14686996 18785514 |
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DOI: | 10.1088/1468-6996/16/5/054203 |