دورية أكاديمية
Renaissance of fly ash as eco-friendly catalysts for rapid CO2 release from amines
| العنوان: | Renaissance of fly ash as eco-friendly catalysts for rapid CO2 release from amines |
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| المؤلفون: | Bhatti, Ali Hassan, Waris, Mamoona, Hussain, Iftikhar, Chougule, Sourabh S., Pasupuleti, Kedhareswara Sairam, Kariim, Ishaq, Bhatti, Umair Hassan, Zhang, Rui |
| المساهمون: | KAUST Catalysis Center (KCC), Physical Science and Engineering (PSE) Division, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 34114, South Korea, University of Science and Technology, 217 Gajeong-ro Yuseong-gu, Daejeon 34113, South Korea, Chungnam National University, 99 Daehak-ro Yuseong-gu, Daejeon 34134, South Korea, Graduate School of Energy Science and Technology, 99 Daehak-ro Yuseong-gu, Daejeon 35015, South Korea, Department of Mechanical Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, Institute of Quantum Systems (IQS), Chungnam National University, 99 Daehak-ro Yuseong-gu, Daejeon 34134, South Korea, Department of Physics, Chungnam National University, 99 Daehak-ro Yuseong-gu, Daejeon 34134, South Korea, Chemical Engineering Department, Federal University of Technology, Minna P. M. B 65, Nigeria, College of Chemical Engineering, Xiangtan University, Xiangtan, Hunan 411105, PR China |
| بيانات النشر: | Elsevier BV |
| سنة النشر: | 2024 |
| المجموعة: | King Abdullah University of Science and Technology: KAUST Repository |
| الوصف: | Catalyst-assisted amine regeneration has emerged as a prominent strategy for enhancing the desorption rate of CO2 from amine solutions at lower temperatures (<100 °C), thereby reducing the massive energy penalty of post-combustion carbon capture process. To make this strategy practical and commercially relevant, it is crucial to develop economically viable, abundant, and eco-friendly catalysts. In this context, we synthesized catalysts from fly ash (FA) through treatment with three acidic solutions of H2SO4, H3PO4, and HNO3 and used them in amine regeneration process with evaluating their catalytic performance in terms of CO2 desorption rate, desorbed CO2 quantity, and regeneration heat duty. The acid treatment increased the BET surface area and generated surface acid sites of the FA, both of which played a vital role in increasing the CO2 desorption from monoethanolamine (MEA) solution at 86 °C. The prepared catalysts increased the CO2 desorption rate by up to 91 % and desorbed CO2 amount by up to 61 %, while reducing the regeneration heat duty by up to 38 % compared to the uncatalyzed amine solution. The studied catalysts could be easily separated and used in successive amine regeneration cycles, which makes them suitable for industrial application. ; The work support from National Natural Science Foundation of China (22008204) is acknowledged. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | unknown |
| تدمد: | 2772-6568 |
| العلاقة: | https://linkinghub.elsevier.com/retrieve/pii/S2772656824000101Test; 2-s2.0-85184749454; Carbon Capture Science and Technology; 100198; http://hdl.handle.net/10754/697371Test; 11 |
| DOI: | 10.1016/j.ccst.2024.100198 |
| الإتاحة: | https://doi.org/10.1016/j.ccst.2024.100198Test http://hdl.handle.net/10754/697371Test |
| حقوق: | Archived with thanks to Carbon Capture Science and Technology under a Creative Commons license, details at: http://creativecommons.org/licenses/by/4.0Test/ ; http://creativecommons.org/licenses/by/4.0Test/ |
| رقم الانضمام: | edsbas.F4D37B43 |
| قاعدة البيانات: | BASE |
Full Text Finder | تدمد: | 27726568 |
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| DOI: | 10.1016/j.ccst.2024.100198 |