التفاصيل البيبلوغرافية
| العنوان: |
CC Bond Formation via Carbon‐Centered Radicals Generated from Dicarbonyl(η 5 ‐cyclopentadienyl) organoiron Complexes |
| المؤلفون: |
Giese, Bernd, Thoma, Gebhard |
| المصدر: |
Helvetica Chimica Acta ; volume 74, issue 5, page 1143-1155 ; ISSN 0018-019X 1522-2675 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
1991 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
Irradiation of benzyldicarbonyl(η 5 ‐cyclopentadienyl)iron complex ( 2 ) leads to hemolytic cleavage of the FeC bond. In the presence of activated alkenes, radical addition occurs and both saturated and unsaturated addition products 7–9 are formed. Photolysis of alkyliron complexes 2 , 3 and 20 in the presence of acrylonitrile leads to the same products as the irradiation of the respective acyliron complexes 28–30 . This indicates that, under photolytical conditions, alkyl and acyl complexes are in equilibrium with each other. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/hlca.19910740524 |
| الإتاحة: |
https://doi.org/10.1002/hlca.19910740524Test |
| حقوق: |
http://onlinelibrary.wiley.com/termsAndConditions#vorTest |
| رقم الانضمام: |
edsbas.F3C570F4 |
| قاعدة البيانات: |
BASE |
