التفاصيل البيبلوغرافية
| العنوان: |
A New Polystyrene–Poly(vinylpyridinium) Ionic Copolymer Dopant for n‐Type All‐Polymer Thermoelectrics with High and Stable Conductivity Relative to the Seebeck Coefficient giving High Power Factor |
| المؤلفون: |
Han, Jinfeng, Tiernan, Emma, Lee, Taein, Chiu, Arlene, McGuiggan, Patty, Adams, Nicholas, Tomko, John A., Hopkins, Patrick E., Thon, Susanna M., Tovar, John D., Katz, Howard E. |
| المساهمون: |
National Science Foundation, Division of Chemistry, Office of Naval Research |
| المصدر: |
Advanced Materials ; volume 34, issue 27 ; ISSN 0935-9648 1521-4095 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2022 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
A novel n‐type copolymer dopant polystyrene–poly(4‐vinyl‐N‐hexylpyridinium fluoride) (PSpF) with fluoride anions is designed and synthesized by reversible addition–fragmentation chain transfer (RAFT) polymerization. This is thought to be the first polymeric fluoride dopant. Electrical conductivity of 4.2 S cm –1 and high power factor of 67 µW m –1 K –2 are achieved for PSpF‐doped polymer films, with a corresponding decrease in thermal conductivity as the PSpF concentration is increased, giving the highest ZT of 0.1. An especially high electrical conductivity of 58 S cm –1 at 88 °C and outstanding thermal stability are recorded. Further, organic transistors of PSpF‐doped thin films exhibit high electron mobility and Hall mobility of 0.86 and 1.70 cm 2 V –1 s –1 , respectively. The results suggest that polystyrene–poly(vinylpyridinium) salt copolymers with fluoride anions are promising for high‐performance n‐type all‐polymer thermoelectrics. This work provides a new way to realize organic thermoelectrics with high conductivity relative to the Seebeck coefficient, high power factor, thermal stability, and broad processing window. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/adma.202201062 |
| الإتاحة: |
https://doi.org/10.1002/adma.202201062Test |
| حقوق: |
http://onlinelibrary.wiley.com/termsAndConditions#amTest ; http://onlinelibrary.wiley.com/termsAndConditions#vorTest |
| رقم الانضمام: |
edsbas.EDD9C83F |
| قاعدة البيانات: |
BASE |
