دورية أكاديمية
Regression analysis of properties of [Au(IPr)(CHR2)] complexes
| العنوان: | Regression analysis of properties of [Au(IPr)(CHR2)] complexes |
|---|---|
| المؤلفون: | Veenboer, Richard M. P., Azofra Mesa, Luis Miguel, Gasperini, Danila, Collado, Alba, Cordes, David B., Slawin, Alexandra M. Z., Cavallo, Luigi, Nolan, Steven P. |
| المساهمون: | 56515319000, 55142490200, 55773018500, 55761921200, 8066427800, 35602399300, 57204926818, 7102048183, 5785127, 1089199, 28176021, 1498959, 30326073, 24922, WOS:Veenboer, RMP, WOS:Azofra, LM, WOS:Gasperini, D, WOS:Collado, A, WOS:Cordes, DB, WOS:Slawin, AMZ, WOS:Cavallo, L, WOS:Nolan, SP |
| المصدر: | Dalton Transactions[ISSN 1477-9226],v. 48 (22), p. 7693-7703 |
| سنة النشر: | 2019 |
| المجموعة: | Universidad de Las Palmas de Gran Canaria: Acceda |
| مصطلحات موضوعية: | 3303 ingeniería y tecnología químicas, N-Heterocyclic Carbene, Equilibrium Acidities, Gold Catalysts, Carbon Acids, Substituent, Ligands, Metal, Au, Reactivity, Mechanism |
| الوصف: | New [Au(IPr)(CHR2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH2R2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR2)] complexes. Variation of the R substituents on the carbanion ligands (CHR2-) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR2)] complexes. ; 7703 ; 7693 |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 1477-9226 1477-9234 |
| العلاقة: | Dalton Transactions; 48; WoS; http://hdl.handle.net/10553/69311Test; 85066850530; 000470709700023; 22; Sí |
| DOI: | 10.1039/c9dt00841a |
| الإتاحة: | https://doi.org/10.1039/c9dt00841aTest http://hdl.handle.net/10553/69311Test |
| رقم الانضمام: | edsbas.DFA45CF3 |
| قاعدة البيانات: | BASE |
| تدمد: | 14779226 14779234 |
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| DOI: | 10.1039/c9dt00841a |