دورية أكاديمية
Ruthenacycles and Iridacycles as Transfer Hydrogenation Catalysts
| العنوان: | Ruthenacycles and Iridacycles as Transfer Hydrogenation Catalysts |
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| المؤلفون: | Ritleng, Vincent, de Vries, Johannes G. |
| المصدر: | Molecules : a journal of synthetic chemistry and natural product chemistry 26 (2021), Nr. 13 |
| بيانات النشر: | MDPI |
| سنة النشر: | 2021 |
| المجموعة: | LeibnizOpen (The Leibniz Association) |
| مصطلحات موضوعية: | Iridium, Ketone, Metallacycle, Oxidation, Ruthenium, Transfer hydrogenation |
| الوقت: | 540 |
| الوصف: | In this review, we describe the synthesis and use in hydrogen transfer reactions of ruthenacycles and iridacycles. The review limits itself to metallacycles where a ligand is bound in bidentate fashion to either ruthenium or iridium via a carbon-metal sigma bond, as well as a dative bond from a heteroatom or an N-heterocyclic carbene. Pincer complexes fall outside the scope. Described are applications in (asymmetric) transfer hydrogenation of aldehydes, ketones, and imines, as well as reductive aminations. Oxidation reactions, i.e., classical Oppenauer oxidation, which is the reverse of transfer hydrogenation, as well as dehydrogenations and oxidations with oxygen, are described. Racemizations of alcohols and secondary amines are also catalyzed by ruthenacycles and iridacycles. ; publishedVersion |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| DOI: | 10.34657/7478 |
| الإتاحة: | https://doi.org/10.34657/7478Test https://oa.tib.eu/renate/handle/123456789/8440Test |
| حقوق: | CC BY 4.0 Unported ; https://creativecommons.org/licenses/by/4.0Test/ |
| رقم الانضمام: | edsbas.D3587021 |
| قاعدة البيانات: | BASE |
| DOI: | 10.34657/7478 |
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