Thermochromic Cholesteric Liquid Crystal Microcapsules with Cellulose Nanocrystals and a Melamine Resin Hybrid Shell

التفاصيل البيبلوغرافية
العنوان: Thermochromic Cholesteric Liquid Crystal Microcapsules with Cellulose Nanocrystals and a Melamine Resin Hybrid Shell
المؤلفون: Tingjiao Yang (11958882), Dong Yuan (6338567), Wei Liu (20030), Zhe Zhang (81603), Kaiyu Wang (192711), Yuxin You (6415949), Huapeng Ye (5813426), Laurens T. de Haan (4242325), Zhen Zhang (86004), Guofu Zhou (2629945)
سنة النشر: 2022
المجموعة: Smithsonian Institution: Digital Repository
مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Cell Biology, Molecular Biology, Biotechnology, Ecology, Developmental Biology, Computational Biology, Space Science, Chemical Sciences not elsewhere classified, various potential applications, smart decorative paints, selective light reflection, resin hybrid shell, relatively high reflectance, melamine – formaldehyde, combine good responsivity, cholesteric liquid crystals, 42 ° c, 30 – 40, wide regulation range, visible wavelength range, stabilized pickering emulsions, obtain coating slurries, mf hybrid shell, fabricate thermochromic coatings, thermochromic coatings, temperature range, pickering emulsifiers
الوصف: Thermochromic coatings that can change their color in response to variations in ambient temperature have various potential applications. Cholesteric liquid crystals (CLCs) are promising thermochromic materials due to their selective light reflection and wide regulation range. However, it remains a challenge to fabricate thermochromic coatings that combine good responsivity, mechanical strength, fabrication feasibility, and flexibility. In this study, CLC microcapsules containing cellulose nanocrystals (CNCs) and a melamine–formaldehyde (MF) resin hybrid shell were fabricated via in situ polymerization using CNC-stabilized Pickering emulsions as templates. The CNCs were employed as both Pickering emulsifiers and alignment agents of CLCs to prepare CLC Pickering emulsions. The CLC microcapsules were mixed with curable binders to obtain coating slurries, and thermochromic coatings were prepared by painting the slurries on substrates and drying. The thermochromic coatings could adjust their color in the visible wavelength range in a temperature range of 12 to 42 °C. Moreover, the obtained thermochromic coatings displayed a relatively high reflectance of up to 30–40% and can even be applied to flexible substrates. The CLC microcapsules with CNCs and an MF hybrid shell are promising in the field of smart decorative paints, anti-counterfeit labels, and artificial skins.
نوع الوثيقة: dataset
اللغة: unknown
العلاقة: https://figshare.com/articles/media/Thermochromic_Cholesteric_Liquid_Crystal_Microcapsules_with_Cellulose_Nanocrystals_and_a_Melamine_Resin_Hybrid_Shell/18585945Test
DOI: 10.1021/acsami.1c23101.s002
الإتاحة: https://doi.org/10.1021/acsami.1c23101.s002Test
حقوق: CC BY-NC 4.0
رقم الانضمام: edsbas.D34BEC65
قاعدة البيانات: BASE