التفاصيل البيبلوغرافية
| العنوان: |
Acyclic Stereocontrol in the Additions of Nucleophilic Alkenes to α‐Chiral N‐Sulfonyl Imines |
| المؤلفون: |
Moore, Lucas C., Lo, Anna, Fell, Jason S., Duong, Matthew R., Moreno, Jose A., Rich, Barry E., Bravo, Martin, Fettinger, James C., Souza, Lucas W., Olmstead, Marilyn M., Houk, Kendall N., Shaw, Jared T. |
| المساهمون: |
National Science Foundation |
| المصدر: |
Chemistry – A European Journal ; volume 25, issue 52, page 12214-12220 ; ISSN 0947-6539 1521-3765 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2019 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
Diastereoselective Lewis acid‐mediated additions of nucleophilic alkenes to N ‐sulfonyl imines are reported. The canonical polar Felkin–Anh model describing additions to carbonyls does not adequately describe analogous additions to N ‐sulfonyl imines. Herein, we describe the development of conditions to produce both syn and anti products with high diastereoselectivity and good yields. A stereoelectronic model consistent with experimental outcomes is also proposed. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/chem.201902790 |
| الإتاحة: |
https://doi.org/10.1002/chem.201902790Test |
| حقوق: |
http://onlinelibrary.wiley.com/termsAndConditions#amTest ; http://onlinelibrary.wiley.com/termsAndConditions#vorTest |
| رقم الانضمام: |
edsbas.BF587F86 |
| قاعدة البيانات: |
BASE |
