دورية أكاديمية
Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins
| العنوان: | Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins |
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| المؤلفون: | Grzhegorzhevskii, K., Haouas, M., Lion, M., Vashurin, A., Denikaev, A., Marfin, Y., Kim, G., Falaise, C., Cadot, E. |
| المصدر: | Chemical Communications |
| بيانات النشر: | Royal Society of Chemistry |
| سنة النشر: | 2022 |
| المجموعة: | Ural Federal University (URFU): ELAR / Уральский федеральный университет: электронный архив УрФУ |
| مصطلحات موضوعية: | MAGNETIC RESONANCE SPECTROSCOPY, NANOSPHERES, PORPHYRINS, MORPHOLOGY, OLIGOMERS, X RAY SCATTERING, CATION, NANOSPHERE, OLIGOMER, POLYANION, POLYOXOMETALATE, PORPHYRIN, UNCLASSIFIED DRUG, CATIONIC PORPHYRIN, HIERARCHICAL ORGANIZATIONS, HYBRID OLIGOMERS, INORGANIC NANOSPHERES, IONIC INTERACTION, MULTISCALE METHOD, NONCOVALENT, PHOTOPHYSICAL, SMALL ANGLE X-RAY SCATTERING, SUPRAMOLECULAR ASSEMBLIES, AQUEOUS SOLUTION, ARTICLE, CHEMICAL STRUCTURE, CONTROLLED STUDY, DIFFUSION COEFFICIENT, MOLECULAR INTERACTION, PROTON NUCLEAR MAGNETIC RESONANCE |
| الوصف: | Noncovalent ionic interactions between nanosized Keplerate-type capsules {Mo132} and tetra-cationic porphyrins have been investigated in aqueous solution using small-angle X-ray scattering, 1H NMR and photophysical methods. These complementary multiscale methods reveal the formation of large hybrid oligomers built from a short-range organization in which the cationic porphyrin is glued onto the large POM surface. The local structuring appears to be strongly dependent on the dye : {Mo132} ratio changing the morphology of the oligomers from linear to dense aggregates. © 2023 The Royal Society of Chemistry. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| تدمد: | 1359-7345 |
| العلاقة: | Grzhegorzhevskii, K, Haouas, M, Lion, M, Vashurin, A, Denikaev, A, Marfin, Y, Kim, G, Falaise, C & Cadot, E 2022, 'Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins', Chemical Communications, Том. 59, № 1, стр. 86-89. https://doi.org/10.1039/D2CC05193ATest; Grzhegorzhevskii, K., Haouas, M., Lion, M., Vashurin, A., Denikaev, A., Marfin, Y., Kim, G., Falaise, C., & Cadot, E. (2022). Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins. Chemical Communications, 59(1), 86-89. https://doi.org/10.1039/D2CC05193ATest; Final; All Open Access; Green Open Access; https://hal.science/hal-03936892/file/Manuscript_Grzhegorzhevskii%20KV_21092022_Revised.pdfTest; http://elar.urfu.ru/handle/10995/132372Test; 85143967787; 902043400001 |
| DOI: | 10.1039/d2cc05193a |
| الإتاحة: | https://doi.org/10.1039/d2cc05193aTest http://elar.urfu.ru/handle/10995/132372Test https://hal.science/hal-03936892/file/Manuscript_Grzhegorzhevskii%20KV_21092022_Revised.pdfTest |
| حقوق: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.A4C6F91F |
| قاعدة البيانات: | BASE |
| تدمد: | 13597345 |
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| DOI: | 10.1039/d2cc05193a |