دورية أكاديمية
Self-Assembly and Host–Guest Interactions of Pd3L2 Metallo-cryptophanes with Photoisomerizable Ligands
| العنوان: | Self-Assembly and Host–Guest Interactions of Pd3L2 Metallo-cryptophanes with Photoisomerizable Ligands |
|---|---|
| المؤلفون: | Britton, E, Ansell, RJ, Howard, MJ, Hardie, MJ |
| بيانات النشر: | American Chemical Society |
| سنة النشر: | 2021 |
| المجموعة: | White Rose Research Online (Universities of Leeds, Sheffield & York) |
| الوصف: | New photoswitchable pyridyl-azo-phenyl-decorated tripodal host ligands (Laz) that belong to the cyclotriveratrylene family have been synthesized, and their photoswitching behavior and crystal structures determined. The latter includes a remarkable 7-fold Borromean-weave entanglement of π–π stacked layers. Trigonal bipyramidal {[Pd(en)]3(Laz)2}6+ metallo-cryptophanes (en = ethylenediamine) were formed from these and a previously known pyridyl-azo-phenyl-decorated tripodal host ligand. These coordination cages dissociate at low concentrations and are less robust to photoswitching of the Laz ligands than were previously reported Ir(III)-linked metallo-cryptophanes with similar ligands, reflecting the greater lability of the Pd–N bonds. The {[Pd(en)]3(Laz)2}6+ cages all act as hosts, binding octyl sulfate anions, or N-[2-(dimethylamino)ethyl]-1,8-naphthalimide in a dimethyl sulfoxide solution. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | text |
| اللغة: | English |
| العلاقة: | https://eprints.whiterose.ac.uk/176569/8/acs.inorgchem.1c01297.pdfTest; Britton, E, Ansell, RJ orcid.org/0000-0001-6189-5248 , Howard, MJ orcid.org/0000-0002-0762-2887 et al. (1 more author) (2021) Self-Assembly and Host–Guest Interactions of Pd3L2 Metallo-cryptophanes with Photoisomerizable Ligands. Inorganic Chemistry, 60 (17). pp. 12912-12923. ISSN 0020-1669 |
| الإتاحة: | https://eprints.whiterose.ac.uk/176569Test/ https://eprints.whiterose.ac.uk/176569/8/acs.inorgchem.1c01297.pdfTest |
| حقوق: | cc_by_4 |
| رقم الانضمام: | edsbas.9A64CCE9 |
| قاعدة البيانات: | BASE |
| الوصف غير متاح. |