التفاصيل البيبلوغرافية
| العنوان: |
Highly Efficient Self-Assembled Activated Carbon Cloth-Templated Photocatalyst for NADH Regeneration and Photocatalytic Reduction of 4-Nitro Benzyl Alcohol |
| المؤلفون: |
Vaibhav Gupta, Rajesh K. Yadav, Ahmad Umar, Ahmed A. Ibrahim, Satyam Singh, Rehana Shahin, Ravindra K. Shukla, Dhanesh Tiwary, Dilip Kumar Dwivedi, Alok Kumar Singh, Atresh Kumar Singh, Sotirios Baskoutas |
| المصدر: |
Catalysts; Volume 13; Issue 4; Pages: 666 |
| بيانات النشر: |
Multidisciplinary Digital Publishing Institute |
| سنة النشر: |
2023 |
| المجموعة: |
MDPI Open Access Publishing |
| مصطلحات موضوعية: |
EC-R@ACC photocatalyst, NADH regeneration, 4-nitro benzyl alcohol, solar light, photocatalytic |
| الوصف: |
This manuscript emphasizes how structural assembling can facilitate the generation of solar chemicals and the synthesis of fine chemicals under solar light, which is a challenging task via a photocatalytic pathway. Solar energy utilization for pollution prevention through the reduction of organic chemicals is one of the most challenging tasks. In this field, a metal-based photocatalyst is an optional technique but has some drawbacks, such as low efficiency, a toxic nature, poor yield of photocatalytic products, and it is expensive. A metal-free activated carbon cloth (ACC)–templated photocatalyst is an alternative path to minimize these drawbacks. Herein, we design the synthesis and development of a metal-free self-assembled eriochrome cyanine R (EC-R) based ACC photocatalyst (EC-R@ACC), which has a higher molar extinction coefficient and an appropriate optical band gap in the visible region. The EC-R@ACC photocatalyst functions in a highly effective manner for the photocatalytic reduction of 4-nitro benzyl alcohol (4-NBA) into 4-amino benzyl alcohol (4-ABA) with a yield of 96% in 12 h. The synthesized EC-R@ACC photocatalyst also regenerates reduced forms of nicotinamide adenine dinucleotide (NADH) cofactor with a yield of 76.9% in 2 h. The calculated turnover number (TON) of the EC-R@ACC photocatalyst for the reduction of 4-nitrobenzyl alcohol is 1.769 × 1019 molecules. The present research sets a new benchmark example in the area of organic transformation and artificial photocatalysis. |
| نوع الوثيقة: |
text |
| وصف الملف: |
application/pdf |
| اللغة: |
English |
| العلاقة: |
Biomass Catalysis; https://dx.doi.org/10.3390/catal13040666Test |
| DOI: |
10.3390/catal13040666 |
| الإتاحة: |
https://doi.org/10.3390/catal13040666Test |
| حقوق: |
https://creativecommons.org/licenses/by/4.0Test/ |
| رقم الانضمام: |
edsbas.8860DCCB |
| قاعدة البيانات: |
BASE |
