التفاصيل البيبلوغرافية
| العنوان: |
High Value-Added Application of Natural Products in Crop Protection: Semisynthesis and Acaricidal Activity of Limonoid-Type Derivatives and Investigation of Their Biocompatible O/W Nanoemulsions as Agronanopesticide Candidates |
| المؤلفون: |
Xiaobo Huang (608424), Min Lv (608418), Qianjun Ma (11766653), Yuanyuan Zhang (101797), Hui Xu (9203) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Pharmacology, Biotechnology, Ecology, Science Policy, Hematology, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, traditional resistant pesticides, provide valuable information, oriented synthetic strategy, key steric configurations, increasingly serious resistance, contain many limonoids, friendly natural product, membered lactam derivatives, b >–, b >-, tetranychus cinnabarinus boisduval, cinnabarinus boisduval, natural products, type derivatives, 10 derivatives, wide range, w nanoemulsions, various wastes, synthesized based, sustainable alternatives, ray crystallography |
| الوصف: |
The increasingly serious resistance of Tetranychus cinnabarinus Boisduval to a wide range of insecticides/acaricides poses a major challenge to their control. The citrus processing industry generates a huge quantity of various wastes that contain many limonoids. To effectively utilize these byproducts and discover more potent green acaricidal molecules as sustainable alternatives for traditional resistant pesticides, various limonoid-type derivatives (halogenated/seven-membered lactam derivatives of obacunone and halogenated/oxime esters/oxime ethers/seven-membered lactam derivatives of limonin) were synthesized based on a diversity-oriented synthetic strategy. The key steric configurations of 10 derivatives were further confirmed by X-ray crystallography. Compound 9m , which displayed greater than 9.7-fold potent acaricidal activity of limonin, was of preeminence. In addition, some interesting structure – activity relationships were observed. Moreover, a biocompatible O/W nanoemulsion delivery system was used to prepare the limonin - based agronanoacaricide, which exhibited pronounced control efficiency against T. cinnabarinus Boisduval in the greenhouse. This systematic investigation will provide valuable information and guidance for future value-added applications of novel eco-friendly natural product-based nanopesticides. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/High_Value-Added_Application_of_Natural_Products_in_Crop_Protection_Semisynthesis_and_Acaricidal_Activity_of_Limonoid-Type_Derivatives_and_Investigation_of_Their_Biocompatible_O_W_Nanoemulsions_as_Agronanopesticide_Candidates/17092133Test |
| DOI: |
10.1021/acs.jafc.1c05450.s001 |
| الإتاحة: |
https://doi.org/10.1021/acs.jafc.1c05450.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.7D487E7C |
| قاعدة البيانات: |
BASE |
