التفاصيل البيبلوغرافية
| العنوان: |
Phosphino‐Phosphination Reactions: Frustrated Lewis Pair Reactivity of Phosphino‐Phosphonium Cations with Alkynes |
| المؤلفون: |
Kim, Hyehwang, Qu, Zheng‐wang, Grimme, Stefan, Al‐Zuhaika, Nahil, Stephan, Douglas W. |
| المساهمون: |
Deutsche Forschungsgemeinschaft |
| المصدر: |
Angewandte Chemie International Edition ; volume 62, issue 43 ; ISSN 1433-7851 1521-3773 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2023 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
The phosphino‐phosphonium cations of the form [R 3 PPR′ 2 ] + are labile and provide access to the constituent Lewis acidic and Lewis basic fragments. This permits frustrated Lewis pair‐type addition reactions to alkynes, affording unprecedented phosphino‐phosphination reactions and giving cations of the form [ cis‐ R 3 PCHC(R′′)PR′ 2 ] + . This reactivity is further adapted to prepare several examples of a rare class of dissymmetric cis‐ olefin‐linked bidentate phosphines. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/anie.202312587 |
| الإتاحة: |
https://doi.org/10.1002/anie.202312587Test |
| حقوق: |
http://creativecommons.org/licenses/by-nc/4.0Test/ |
| رقم الانضمام: |
edsbas.68F2A8F5 |
| قاعدة البيانات: |
BASE |
