دورية أكاديمية
Effect of B 2 O 3 /P 2 O 5 substitution on the properties and structure of tin boro-phosphate glasses
| العنوان: | Effect of B 2 O 3 /P 2 O 5 substitution on the properties and structure of tin boro-phosphate glasses |
|---|---|
| المؤلفون: | Saitoh, A., Tricot, G., Rajbhandari, P., Anan, S., Takebe, H. |
| المساهمون: | Graduate School of Science and Engineering, Ehime University Matsuyama, Japon, Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 (LASIRE), Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) |
| المصدر: | ISSN: 0254-0584 ; Materials Chemistry and Physics ; https://hal.science/hal-01168263Test ; Materials Chemistry and Physics, 2015, 149 - 150, pp.648 - 656. ⟨10.1016/j.matchemphys.2014.11.021⟩. |
| بيانات النشر: | HAL CCSD Elsevier |
| سنة النشر: | 2015 |
| مصطلحات موضوعية: | Glasses, Oxides, Fourier transform infrared spectroscopy (FTIR), Nuclear magnetic resonance (NMR), Raman spectroscopy and scattering, Thermal properties, [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry, geo, envir |
| الوصف: | Effect of B 2 O 3 /P 2 O 5 substitution on the properties and structure of the ternary 67SnO–(33–x)P 2 O 5 –xB 2 O 3 composition line (from x = 0–33 mol%) are examined in this contribution. We show that density and glass transition temperature increase while molar volume and thermal expansion coefficient decrease with increasing B 2 O 3 concentration. Density and thermal properties experience an original three-domain evolution with rapid (region I: 0 ≤ x < 5), substantial (II: 5 < x ≤ 15), and moderate (III: 15 < x ≤ 33) increase. In order to explain this unconventional behaviour, the glass structure has been investigated using high magnetic field 1 dimensional 31 P and 11 B MAS–NMR, micro-Raman and infrared spectroscopies. 11 B MAS–NMR experiments allow to (i) monitor the 3- and 4-fold coordinated borate species proportion and (ii) highlight the presence of unreported 4-fold coordinated species in the region (III). Finally, it is shown that substitution of P 2 O 5 by B 2 O 3 induces an alteration of the dimeric phosphate network and formation of mixed anion structure that consists of Q 0 phosphate units, 3- and 4-fold coordinated borate units and their combinations. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| العلاقة: | https://hal.science/hal-01168263Test |
| الإتاحة: | https://doi.org/10.1016/j.matchemphys.2014.11.021Test https://hal.science/hal-01168263Test |
| حقوق: | undefined |
| رقم الانضمام: | edsbas.65F4A6EC |
| قاعدة البيانات: | BASE |
| الوصف غير متاح. |