دورية أكاديمية
Circularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb( iii ) single-molecule magnets
العنوان: | Circularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb( iii ) single-molecule magnets |
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المؤلفون: | Mattei, Carlo Andrea, Montigaud, Vincent, Lefeuvre, Bertrand, Dorcet, Vincent, Argouarch, Gilles, Cador, Olivier, Le Guennic, Boris, Maury, Olivier, Lalli, Claudia, Guyot, Yannick, Guy, Stéphan, Gindre, Cyprien, Bensalah-Ledoux, Amina, Riobé, François, Baguenard, Bruno, Pointillart, Fabrice |
المساهمون: | Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Chimie - UMR5182 (LC), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), iLM - Luminescence (iLM - LUMINESCENCE), Institut Lumière Matière Villeurbanne (ILM), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS), iLM - Matériaux et nanostructures photoniques (iLM - MNP), Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), This work was supported by CNRS, Université de Rennes, the European Research Council through the ERC-CoG 725184 MULTIPROSMM (project no. 725184) and the Agence Nationale de la Recherche (SMMCPL ANR-19-CE29-0012-02)., ANR-19-CE29-0012,SMMCPL,Luminescence polarisée circulairement de molécules-aimants à base de lanthanide(2019), European Project: 725184,H2020-EU.1.1. - EXCELLENT SCIENCE - European Research Council (ERC),MULTIPROSMM(2017) |
المصدر: | ISSN: 2050-7526. |
بيانات النشر: | HAL CCSD Royal Society of Chemistry |
سنة النشر: | 2023 |
المجموعة: | Université de Rennes 1: Publications scientifiques (HAL) |
مصطلحات موضوعية: | [CHIM.COOR]Chemical Sciences/Coordination chemistry, [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry |
الوصف: | International audience ; Lanthanide ions have attracted great interest owing to their optical and magnetic properties. Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years. Moreover, chiral lanthanide complexes allow the observation of remarkable circularly polarized luminescence (CPL). However, the combination of both SMM and CPL behaviors in a single molecular system is very rare and deserves attention in the design of multifunctional materials. Four chiral one-dimensional coordination compounds involving 1,1′-Bi-2-naphtol (BINOL)-derived bisphosphate ligands and the Yb(III) centre were synthesized and characterized by powder and single-crystal X-ray diffraction. All the Yb(III)-based polymers displayed field-induced SMM behavior with magnetic relaxation occurring by applying Raman processes and near infrared CPL in the solid state. |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | English |
العلاقة: | info:eu-repo/grantAgreement//725184/EU/MULtiple PROperties Single Molecule Magnets/MULTIPROSMM; hal-04127855; https://hal.science/hal-04127855Test; https://hal.science/hal-04127855/documentTest; https://hal.science/hal-04127855/file/2023-061.pdfTest |
DOI: | 10.1039/d3tc00858d |
الإتاحة: | https://doi.org/10.1039/d3tc00858dTest https://hal.science/hal-04127855Test https://hal.science/hal-04127855/documentTest https://hal.science/hal-04127855/file/2023-061.pdfTest |
حقوق: | http://creativecommons.org/licenses/by-ncTest/ ; info:eu-repo/semantics/OpenAccess |
رقم الانضمام: | edsbas.5D11BE08 |
قاعدة البيانات: | BASE |
DOI: | 10.1039/d3tc00858d |
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