دورية أكاديمية

Circularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb( iii ) single-molecule magnets

التفاصيل البيبلوغرافية
العنوان: Circularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb( iii ) single-molecule magnets
المؤلفون: Mattei, Carlo Andrea, Montigaud, Vincent, Lefeuvre, Bertrand, Dorcet, Vincent, Argouarch, Gilles, Cador, Olivier, Le Guennic, Boris, Maury, Olivier, Lalli, Claudia, Guyot, Yannick, Guy, Stéphan, Gindre, Cyprien, Bensalah-Ledoux, Amina, Riobé, François, Baguenard, Bruno, Pointillart, Fabrice
المساهمون: Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Chimie - UMR5182 (LC), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), iLM - Luminescence (iLM - LUMINESCENCE), Institut Lumière Matière Villeurbanne (ILM), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS), iLM - Matériaux et nanostructures photoniques (iLM - MNP), Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), This work was supported by CNRS, Université de Rennes, the European Research Council through the ERC-CoG 725184 MULTIPROSMM (project no. 725184) and the Agence Nationale de la Recherche (SMMCPL ANR-19-CE29-0012-02)., ANR-19-CE29-0012,SMMCPL,Luminescence polarisée circulairement de molécules-aimants à base de lanthanide(2019), European Project: 725184,H2020-EU.1.1. - EXCELLENT SCIENCE - European Research Council (ERC),MULTIPROSMM(2017)
المصدر: ISSN: 2050-7526.
بيانات النشر: HAL CCSD
Royal Society of Chemistry
سنة النشر: 2023
المجموعة: Université de Rennes 1: Publications scientifiques (HAL)
مصطلحات موضوعية: [CHIM.COOR]Chemical Sciences/Coordination chemistry, [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry
الوصف: International audience ; Lanthanide ions have attracted great interest owing to their optical and magnetic properties. Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years. Moreover, chiral lanthanide complexes allow the observation of remarkable circularly polarized luminescence (CPL). However, the combination of both SMM and CPL behaviors in a single molecular system is very rare and deserves attention in the design of multifunctional materials. Four chiral one-dimensional coordination compounds involving 1,1′-Bi-2-naphtol (BINOL)-derived bisphosphate ligands and the Yb(III) centre were synthesized and characterized by powder and single-crystal X-ray diffraction. All the Yb(III)-based polymers displayed field-induced SMM behavior with magnetic relaxation occurring by applying Raman processes and near infrared CPL in the solid state.
نوع الوثيقة: article in journal/newspaper
اللغة: English
العلاقة: info:eu-repo/grantAgreement//725184/EU/MULtiple PROperties Single Molecule Magnets/MULTIPROSMM; hal-04127855; https://hal.science/hal-04127855Test; https://hal.science/hal-04127855/documentTest; https://hal.science/hal-04127855/file/2023-061.pdfTest
DOI: 10.1039/d3tc00858d
الإتاحة: https://doi.org/10.1039/d3tc00858dTest
https://hal.science/hal-04127855Test
https://hal.science/hal-04127855/documentTest
https://hal.science/hal-04127855/file/2023-061.pdfTest
حقوق: http://creativecommons.org/licenses/by-ncTest/ ; info:eu-repo/semantics/OpenAccess
رقم الانضمام: edsbas.5D11BE08
قاعدة البيانات: BASE