التفاصيل البيبلوغرافية
| العنوان: |
Poly(divinylbenzene-maleic acid) Hollow Nanospheres Coordinated with Zirconium: An Effective Catalyst for the Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol |
| المؤلفون: |
Siyu Sun, Lutong Jiao, Peijun Ji |
| سنة النشر: |
2024 |
| المجموعة: |
Smithsonian Institution: Figshare |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Molecular Biology, Biotechnology, Sociology, Immunology, Inorganic Chemistry, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, two aspects contribute, catalytic transfer hydrogenation, carboxylic acid groups, high catalytic efficiency, hollow nanospheres coordinated, 4 +, zr hollow nanospheres, furfuryl alcohol poly, hollow nanospheres, furfuryl alcohol, maleic acid, high content, high accessibility, zr possesses, effective catalyst, confinement coordination |
| الوصف: |
Poly(divinylbenzene-maleic acid) (PDBMA) hollow nanospheres with a high content of carboxylic acid groups were prepared. Through the confinement coordination of Zr 4+ ions with the carboxylic acid groups of the backbone of PDBMA, the hybrid PDBMA&Zr hollow nanospheres were synthesized. PDBMA&Zr possesses a high content of coordinatively unsaturated zirconium sites (Zr cus ). PDBMA&Zr exhibited significantly high catalytic efficiency for the catalytic transfer hydrogenation of furfural to furfuryl alcohol. Two aspects contribute to high catalytic efficiency: the high content of coordinatively unsaturated zirconium sites and the high accessibility of zirconium sites by the reactant furfural. The mechanism for the catalytic transfer hydrogenation reaction by PDBMA&Zr has been investigated. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/Poly_divinylbenzene-maleic_acid_Hollow_Nanospheres_Coordinated_with_Zirconium_An_Effective_Catalyst_for_the_Catalytic_Transfer_Hydrogenation_of_Furfural_to_Furfuryl_Alcohol/25429652Test |
| DOI: |
10.1021/acs.iecr.3c04287.s001 |
| الإتاحة: |
https://doi.org/10.1021/acs.iecr.3c04287.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.51E00958 |
| قاعدة البيانات: |
BASE |
