دورية أكاديمية
Direct Synthesis of Thiocarbamoyl Fluorides and Trifluoromethylamines Through Fluorinative Desulfurization
| العنوان: | Direct Synthesis of Thiocarbamoyl Fluorides and Trifluoromethylamines Through Fluorinative Desulfurization |
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| المؤلفون: | Onida, Killian, Vanoye, Laurent, Tlili, Anis |
| المساهمون: | Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (ICBMS), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École Supérieure de Chimie Physique Électronique de Lyon (CPE)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Génie des Procédés Catalytiques (LGPC), Université de Lyon-Université de Lyon-École Supérieure de Chimie Physique Électronique de Lyon (CPE)-Centre National de la Recherche Scientifique (CNRS) |
| المصدر: | ISSN: 1434-193X. |
| بيانات النشر: | HAL CCSD Wiley-VCH Verlag |
| سنة النشر: | 2019 |
| المجموعة: | Université de Lyon: HAL |
| مصطلحات موضوعية: | [CHIM]Chemical Sciences |
| الوصف: | International audience ; Herein, a straightforward synthesis of thiocarbamoyl fluorides is reported starting from amines and carbon disulfide. The key to success is the fluorinative desulfurization of carbon disulfide with (diethylamino)sulfurtrifluroide (DAST). The title compounds were obtained in moderate to very good isolated yields. Furthermore, we demonstrated also that thiocarbamoyl fluoride can be converted to their trifluoromethyl amine analogues through simple treatment with silver fluoride. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| العلاقة: | hal-03008845; https://hal.science/hal-03008845Test; https://hal.science/hal-03008845/documentTest; https://hal.science/hal-03008845/file/EurJOC%20CS2%20Accepted%20idhall.pdfTest |
| DOI: | 10.1002/ejoc.201901113 |
| الإتاحة: | https://doi.org/10.1002/ejoc.201901113Test https://hal.science/hal-03008845Test https://hal.science/hal-03008845/documentTest https://hal.science/hal-03008845/file/EurJOC%20CS2%20Accepted%20idhall.pdfTest |
| حقوق: | info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.4C336071 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/ejoc.201901113 |
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