التفاصيل البيبلوغرافية
| العنوان: |
Fast Delayed Emission in New Pyridazine-Based Compounds |
| المؤلفون: |
Krotkus, Simonas, Matulaitis, Tomas, Diesing, Stefan, Copley, Graeme, Archer, Emily, Keum, Changmin, Cordes, David B., Slawin, Alexandra M. Z., Gather, Malte C., Zysman-Colman, Eli, Samuel, Ifor D. W. |
| المساهمون: |
Engineering and Physical Sciences Research Council, European Commission, National Research Foundation of Korea |
| المصدر: |
Frontiers in Chemistry ; volume 8 ; ISSN 2296-2646 |
| بيانات النشر: |
Frontiers Media SA |
| سنة النشر: |
2021 |
| المجموعة: |
Frontiers (Publisher - via CrossRef) |
| مصطلحات موضوعية: |
General Chemistry |
| الوصف: |
Three novel donor-acceptor molecules comprising the underexplored pyridazine (Pydz) acceptor moiety have been synthesized and their structural, electrochemical and photophysical properties thoroughly characterized. Combining Pydz with two phenoxazine donor units linked via a phenyl bridge in a meta configuration ( dPXZMePydz ) leads to high reverse intersystem crossing rate k RISC = 3.9 · 10 6 s −1 and fast thermally activated delayed fluorescence (TADF) with <500 ns delayed emission lifetime. Efficient triplet harvesting via the TADF mechanism is demonstrated in OLEDs using dPXZMePydz as the emitter but does not occur for compounds bearing weaker donor units. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| DOI: |
10.3389/fchem.2020.572862 |
| DOI: |
10.3389/fchem.2020.572862/full |
| الإتاحة: |
https://doi.org/10.3389/fchem.2020.572862Test |
| حقوق: |
https://creativecommons.org/licenses/by/4.0Test/ |
| رقم الانضمام: |
edsbas.32A7B821 |
| قاعدة البيانات: |
BASE |
