دورية أكاديمية
Mercury deposition in the Eastern Mediterranean: Modern fluxes in the water column and Holocene accumulation rates in abyssal sediment
| العنوان: | Mercury deposition in the Eastern Mediterranean: Modern fluxes in the water column and Holocene accumulation rates in abyssal sediment |
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| المؤلفون: | Cossa, Daniel, Guédron, S., Coquery, Marina, Calafat, A., Zuñiga, D., Stavrakakis, S., Radakovitch, Olivier, Buscail, R., García-Orellana, J., Heussner, S. |
| المساهمون: | Unité Contamination Chimique des Ecosystèmes Marins (CCEM), Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER), Institut des Sciences de la Terre (ISTerre), Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement IRD : UR219-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 ), RiverLy - Fonctionnement des hydrosystèmes (RiverLy), Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Departament de Dinàmica de la Terra i de l’Oceà Barcelona, Universitat de Barcelona (UB), Consejo Superior de Investigaciones Cientificas España = Spanish National Research Council Spain (CSIC), Newcastle University Newcastle, Centre européen de recherche et d'enseignement des géosciences de l'environnement (CEREGE), Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Collège de France (CdF (institution))-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Laboratoire de recherche sur les transferts des radionucléides dans les écosystèmes aquatiques (IRSN/PSE-ENV/SRTE/LRTA), Service de recherche sur les transferts et les effets des radionucléides sur les écosystèmes (IRSN/PSE-ENV/SRTE), Institut de Radioprotection et de Sûreté Nucléaire (IRSN)-Institut de Radioprotection et de Sûreté Nucléaire (IRSN), Centre de Formation et de Recherche sur les Environnements Méditérranéens (CEFREM), Université de Perpignan Via Domitia (UPVD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Universitat Autònoma de Barcelona = Autonomous University of Barcelona = Universidad Autónoma de Barcelona (UAB), IFREMER - Institut Français de Recherche pour l'Exploitation de la Mer, European Community - ADIOS MAST program (EVK3-CT-2000-00035, Atmospheric deposition, and impact of pollutants on the open Mediterranean Sea) |
| المصدر: | ISSN: 0009-2541 ; Chemical Geology ; https://hal.science/hal-04309396Test ; Chemical Geology, 2023, 636, pp.121652. ⟨10.1016/j.chemgeo.2023.121652⟩. |
| بيانات النشر: | HAL CCSD Elsevier |
| سنة النشر: | 2023 |
| المجموعة: | Université Savoie Mont Blanc: HAL |
| مصطلحات موضوعية: | Mercury, Mediterranean, Flux, Accumulation rates, Sediment traps, Sediment core, [SDV]Life Sciences [q-bio] |
| الوصف: | International audience ; Modern and past mercury (Hg) fluxes in the oceanic water column and abyssal sediments are poorly quantified. Here, we investigated the particulate transfer of Hg in the water column of the ultra-oligotrophic Ionian Sea (Eastern Mediterranean) with sediment traps during a one-year period, and its accumulation in the deep central abyssal plain using sediment cores comprising the last 10 ka. The Hg concentrations in the particles collected in the sediment traps varied from 112 to 401 ng g−1 and enabled quantifying annual Hg fluxes of 2.0, 2.5, and 2.5 μg m−2 a−1, for traps deployed at 250, 1440, and 2820 m deep, respectively. Hg collected in the upper trap originates from atmospheric deposition, including Saharan dust, which is scavenged by the biological pump. Higher Hg fluxes found at mid-depth and near-bottom than in the upper water layer are attributed to lateral advection under the mixed layer of Hg-rich resuspended sediments from the Adriatic continental margin. In the abyssal sediment, Hg concentrations range from 15 to 134 ng g−1 with the highest levels in the Sapropel S1. Methylmercury concentrations varied from 0.06 to 0.24 ng g−1 following the distribution of total Hg, with evidence of its specific accumulation at the oxidized front of the sapropel. We estimated that <1.8% of the total Hg in the sedimentary column was diagenetically reallocated. The reconstruction of historical Hg accumulation rates (HgAR) during the Holocene shows low pre-anthropogenic values (~0.3 μg m2 a−1 before 4 ka BP), increasing up to ~0.9 μg m2 a−1 during the late Iron Age and the Roman period (1.5–2.5 ka BP), and up to 2.9 μg m2 a−1 during the Industrial Era. During the Sapropel S1 period (~6–10 ka BP), HgARs rose to 6.4 μg m−2 a−1 likely due to the intensity of the Hg removal by the biological pump, the organic matter preservation, along with high inputs of Hg-rich terrigenous matter and a possible restricted recycling in the atmosphere. Hg accumulation in the Ionian Sea deep sediment is found ... |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| العلاقة: | hal-04309396; https://hal.science/hal-04309396Test; WOS: 001055065300001 |
| DOI: | 10.1016/j.chemgeo.2023.121652 |
| الإتاحة: | https://doi.org/10.1016/j.chemgeo.2023.121652Test https://hal.science/hal-04309396Test |
| رقم الانضمام: | edsbas.2EBE4DF0 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1016/j.chemgeo.2023.121652 |
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