التفاصيل البيبلوغرافية
| العنوان: |
Ring Expansion to 6‐, 7‐, and 8‐Membered Benzosilacycles through Strain‐Release Silicon‐Based Cross‐Coupling |
| المؤلفون: |
Qin, Ying, Han, Jie‐Lian, Ju, Cheng‐Wei, Zhao, Dongbing |
| المصدر: |
Angewandte Chemie ; volume 132, issue 22, page 8559-8563 ; ISSN 0044-8249 1521-3757 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2020 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
The synthesis of silacycles is highly appealing due to their important applications in organic synthesis, medicinal chemistry, and materials chemistry. However, sila‐tetralins and sila‐benzosuberanes are surprisingly under‐represented due to a lack of general methods to access these compounds. We successfully developed a Pd‐catalyzed strain‐release silicon‐based cross‐coupling as an unprecedented ring‐expansion method, which constitutes a general route for preparing diverse sila‐tetralins and sila‐benzosuberanes. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/ange.202001539 |
| الإتاحة: |
https://doi.org/10.1002/ange.202001539Test |
| حقوق: |
http://onlinelibrary.wiley.com/termsAndConditions#vorTest |
| رقم الانضمام: |
edsbas.2CCE7BD7 |
| قاعدة البيانات: |
BASE |
