التفاصيل البيبلوغرافية
| العنوان: |
Selectfluor-Promoted Reactions of Aryl Methyl Ketones with Dimethyl Sulfoxide to Give 2,5-Diacylthiophenes and β‑Acyl Allylic Methylsulfones |
| المؤلفون: |
Hao Lu (354247), Jiayi Chen (3358625), Wenjun Zhou (310993), Lifen Peng (1581322), Shuang-Feng Yin (1478986), Nobuaki Kambe (1621282), Renhua Qiu (1478992) |
| سنة النشر: |
2023 |
| مصطلحات موضوعية: |
Biochemistry, Microbiology, Genetics, Molecular Biology, Pharmacology, Cancer, Plant Biology, Chemical Sciences not elsewhere classified, simple solvent modification, different solvent ratios, acyl allylic methylsulfones, promoted cascade cyclization, aryl methyl ketones, methyl ketones, promoted reactions, selectively introduced, method enables, excellent chemoselectivity, dimethyl sulfoxide, coupling reactions, convenient synthesis, c –, bonds via |
| الوصف: |
In this paper, a convenient synthesis of 2,5-diacylthiophenes and β-acyl allylic methylsulfones from aryl methyl ketones with dimethyl sulfoxide (DMSO) through Selectfluor-promoted cascade cyclization and cross-coupling reactions by simple solvent modification is described. This method enables the formation of new C–C and C–S bonds via the selection of different solvent ratios, in which DMSO molecules as synthons can be selectively introduced into methyl ketones. The features of this transformation include readily available starting materials, excellent chemoselectivity, and good functional group tolerance. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/Selectfluor-Promoted_Reactions_of_Aryl_Methyl_Ketones_with_Dimethyl_Sulfoxide_to_Give_2_5-Diacylthiophenes_and_Acyl_Allylic_Methylsulfones/21829988Test |
| DOI: |
10.1021/acs.orglett.2c04101.s002 |
| الإتاحة: |
https://doi.org/10.1021/acs.orglett.2c04101.s002Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.253B8E83 |
| قاعدة البيانات: |
BASE |
