Mn(Pt$_{1-x}$Pd$_{x}$)$_5$P: Isovalent Tuning of Mn Sublattice Magnetic Order

التفاصيل البيبلوغرافية
العنوان: Mn(Pt$_{1-x}$Pd$_{x}$)$_5$P: Isovalent Tuning of Mn Sublattice Magnetic Order
المؤلفون: Slade, Tyler J., Mudiyanselage, Ranuri S. Dissanayaka, Furukawa, Nao, Smith, Tanner R., Schmidt, Juan, Wang, Lin-Lin, Kang, Chang-Jong, Wei, Kaya, Shu, Zhixue, Kong, Tai, Baumbach, Ryan, Kotliar, Gabriel, Budko, Sergey L., Xie, Weiwei, Canfield, Paul C.
سنة النشر: 2022
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: We report the growth and characterization of MnPd$_5$P, a ferromagnet with T$_C$ $\approx$ 295 K, and conduct a substitutional study with its antiferromagnetic analogue MnPt$_5$P. We grow single crystals of MnPd$_5$P and Mn(Pt$_{1-x}$Pd$_x$)$_5$P by adding Mn into (Pt$_{1-x}$Pd$_{x}$)-P based melts. All compounds in the family adopt the layered anti-CeCoIn$_5$ structure with space group P4/mmm, and EDS and XRD results indicate that MnPt$_5$P and MnPd$_5$P form a solid solution. Based on magnetization and resistance data, we construct a T-x phase diagram for Mn(Pt$_{1-x}$Pd$_x$)$_5$P and demonstrate the antiferromagnetic order found in MnPt$_5$P is extraordinarily sensitive to Pd substitution. At low Pd fractions (x $<$ 0.010), the single antiferromagnetic transition in pure MnPt$_5$P splits into a higher temperature ferromagnetic transition followed on cooling by a lower temperature ferromagnetic to antiferromagnetic transition and then by a re-entrant antiferromagnetic to ferromagnetic transition at lower temperatures. The antiferromagnetic region makes up a bubble that persists to x $\approx$ 0.009 for T $\approx$ 150 K, with all samples x $<$ 0.009 recovering their initial ferromagnetic state with further cooling to base temperature. Over the same low x range we find a non-monotonic change in the room temperature unit cell volume, further suggesting that pure MnPt$_5$P is close to an instability. Once x $>$ 0.010, Mn(Pt$_{1-x}$Pd$_x$)$_5$P undergoes a single ferromagnetic transition. The Curie temperature increases rapidly with x, rising from T$_C$ $\approx$ 197 K at x = 0.013 to a maximum of T$_C$ $\approx$ 312 K for x $\approx$ 0.62, and then falls back to T$_C$ $\approx$ 295 K for pure MnPd$_5$P (x = 1). Given that Pt and Pd are isoelectronic, this work raises questions as to the origin of the extreme sensitivity of the magnetic ground state in MnPt$_5$P upon introducing Pd.
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevB.107.134429
الوصول الحر: http://arxiv.org/abs/2211.01818Test
رقم الانضمام: edsarx.2211.01818
قاعدة البيانات: arXiv