A non-energetic mechanism for glycine formation in the interstellar medium

التفاصيل البيبلوغرافية
العنوان: A non-energetic mechanism for glycine formation in the interstellar medium
المؤلفون: Ioppolo, S., Fedoseev, G., Chuang, K. -J., Cuppen, H. M., Clements, A. R., Jin, M., Garrod, R. T., Qasim, D., Kofman, V., van Dishoeck, E. F., Linnartz, H.
المصدر: Nature Astronomy published online 16 November 2020
سنة النشر: 2020
المجموعة: Astrophysics
Physics (Other)
مصطلحات موضوعية: Astrophysics - Instrumentation and Methods for Astrophysics, Astrophysics - Earth and Planetary Astrophysics, Astrophysics - Astrophysics of Galaxies, Astrophysics - Solar and Stellar Astrophysics, Physics - Chemical Physics
الوصف: The detection of the amino acid glycine and its amine precursor methylamine on the comet 67P/Churyumov-Gerasimenko by the Rosetta mission provides strong evidence for a cosmic origin of prebiotics on Earth. How and when such complex organic molecules form along the process of star- and planet-formation remains debated. We report the first laboratory detection of glycine formed in the solid phase through atom and radical-radical addition surface reactions under cold dense interstellar cloud conditions. Our experiments, supported by astrochemical models, suggest that glycine forms without the need for energetic irradiation, such as UV photons and cosmic rays, in interstellar water-rich ices, where it remains preserved, in a much earlier star-formation stage than previously assumed. We also confirm that solid methylamine is an important side-reaction product. A prestellar formation of glycine on ice grains provides the basis for a complex and ubiquitous prebiotic chemistry in space enriching the chemical content of planet-forming material.
Comment: Preprint of the original submitted version
نوع الوثيقة: Working Paper
DOI: 10.1038/s41550-020-01249-0
الوصول الحر: http://arxiv.org/abs/2011.06145Test
رقم الانضمام: edsarx.2011.06145
قاعدة البيانات: arXiv