Direct imaging of orbitals in quantum materials

التفاصيل البيبلوغرافية
العنوان: Direct imaging of orbitals in quantum materials
المؤلفون: Yavaş, Hasan, Sundermann, Martin, Chen, Kai, Amorese, Andrea, Severing, Andrea, Gretarsson, Hlynur, Haverkort, Maurits W., Tjeng, Liu Hao
المصدر: Nature Physics 15, 559 (2019)
سنة النشر: 2019
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Strongly Correlated Electrons
الوصف: The spectacular physical properties of quantum materials based on transition metal, rare earth, and actinide elements continue to challenge our comprehension of solid state physics and chemistry. The electronic states of these materials are dominated by the $d$ and $f$ wave functions intertwined with the strong band formation of the solid. In order to estimate which wave functions contribute to the ground state formation, we have had to rely, until now, on theoretical calculations combined with spectroscopy. Here we show that $s$-core-level non-resonant inelastic x-ray scattering ($s$-NIXS) can directly image the active orbital in real space, without the necessity of any modeling. The power and accuracy of this new technique is shown using the text-book example, x$^2$-y$^2$/3$z^2$-r$^2$ orbital of the Ni$^{2+}$ ion in NiO single crystal.
Comment: 6 pages, 4 figures
نوع الوثيقة: Working Paper
DOI: 10.1038/s41567-019-0471-2
الوصول الحر: http://arxiv.org/abs/1902.07128Test
رقم الانضمام: edsarx.1902.07128
قاعدة البيانات: arXiv