Arylsulfonyl Group: Activating Properties and Recent Synthetic Applications
| العنوان: | Arylsulfonyl Group: Activating Properties and Recent Synthetic Applications |
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| المؤلفون: | Marino Petrini, Fabio Martinelli, Alessandro Palmieri |
| المصدر: | Phosphorus, Sulfur, and Silicon and the Related Elements. 186:1032-1045 |
| بيانات النشر: | Informa UK Limited, 2011. |
| سنة النشر: | 2011 |
| مصطلحات موضوعية: | Inorganic Chemistry, Sulfonyl, chemistry.chemical_classification, Nucleophilic addition, chemistry, Group (periodic table), Stereochemistry, Organic Chemistry, Leaving group, Enantioselective synthesis, Moiety, Biochemistry, Carbanion |
| الوصف: | The carbanion stabilizing effect induced by the arylsulfonyl group has dominated and typified the chemistry of this functional entity for a long time. In addition to this important feature, the activity of the arylsulfonyl moiety as a leaving group has been exploited and a plethora of exciting synthetic applications have been found. The base- or acid-promoted elimination of the sulfonyl group from of α-amido sulfones and sulfonyl indoles is able to produce the in situ generation of reactive N-acylimino and alkylideneindolenine intermediates that can be used in the diastereo and enantioselective synthesis of various amino and heterocyclic compounds. |
| تدمد: | 1563-5325 1042-6507 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eee387ecbe6cd34dce9912116a3f38faTest https://doi.org/10.1080/10426507.2010.522631Test |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....eee387ecbe6cd34dce9912116a3f38fa |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15635325 10426507 |
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