Organocatalytic Cascade β-Functionalization/Aromatization of Pyrrolidines via Double Hydride Transfer
| العنوان: | Organocatalytic Cascade β-Functionalization/Aromatization of Pyrrolidines via Double Hydride Transfer |
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| المؤلفون: | Jian Xiao, Xian-Jiang Li, Lan Zhou, Shuo Yang, Chang-Lun Shao, Xiao-De An, Qing Liu |
| المصدر: | Organic Letters. 22:776-780 |
| بيانات النشر: | American Chemical Society (ACS), 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | chemistry.chemical_compound, Trifluoromethyl, chemistry, Cascade, Hydride, Organic Chemistry, Aromatization, Surface modification, Physical and Theoretical Chemistry, Biochemistry, Combinatorial chemistry |
| الوصف: | An unprecedented cascade β-functionalization/aromatization reaction of N-arylpyrrolidines was established. A series of β-substituted arylpyrroles embedded with trifluoromethyl groups are provided directly from N-arylpyrrolidines. The deuterium-labeling experiments indicate that sequential double hydride transfer processes serve as the key steps in this transformation. |
| تدمد: | 1523-7052 1523-7060 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e86e9ba2a96dc37ebbdd6a3e31298279Test https://doi.org/10.1021/acs.orglett.9b03918Test |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....e86e9ba2a96dc37ebbdd6a3e31298279 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15237052 15237060 |
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