Intersystem crossing in thiobases proceeds by a dark intermediate state
| العنوان: | Intersystem crossing in thiobases proceeds by a dark intermediate state |
|---|---|
| المؤلفون: | Lucia Ganzer, Artur Nenov, Marco Garavelli, Irene Conti, Giulio Cerullo, Barbara E. Nogueira de Faria, Danielle Cristina Teles-Ferreira, Ana M. de Paula, Rocio Borrego-Varillas, Cristian Manzoni, Sandro De Silvestri |
| المساهمون: | Cerullo, G., Teles-Ferreira, Danielle Cristina, Borrego-Varillas, Rocio, Ganzer, Lucia, Nogueira Faria, Barbara Elza, Manzoni, Cristian, De Silvestri, Sandro, Nenov, Artur, Conti, Irene, Garavelli, Marco, Cerullo, Giulio, de Paula, Ana Maria |
| المصدر: | EPJ Web of Conferences, Vol 205, p 10005 (2019) |
| بيانات النشر: | EDP Sciences, 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Materials science, 010308 nuclear & particles physics, Physics, QC1-999, 01 natural sciences, Molecular physics, Intersystem crossing thiobases QM/MM conical intersections, Intersystem crossing, 0103 physical sciences, Ultrafast laser spectroscopy, Relaxation (physics), Intermediate state, 010306 general physics, Spectroscopy |
| الوصف: | 4-thiouracil (4TU) is studied by transient absorption spectroscopy employing sub-20 fs UV-pulses and hybrid QM(CASPT2) / MM(AMBER) computations (static and dynamic), evidencing that, along the photoexcited relaxation pathway, intersystem crossing originates from a dark intermediate state. |
| وصف الملف: | STAMPA |
| اللغة: | English |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d0ce25bd7b821ab666132dcbb7e79559Test https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_10005.pdfTest |
| حقوق: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....d0ce25bd7b821ab666132dcbb7e79559 |
| قاعدة البيانات: | OpenAIRE |
| الوصف غير متاح. |