Molecules
| العنوان: | Molecules |
|---|---|
| المؤلفون: | Joseph S. Merola, Michael A. G. Berg, Hannah M. Rogers, David B. Hobart |
| المساهمون: | Chemistry |
| المصدر: | Molecules Molecules, Vol 26, Iss 4331, p 4331 (2021) Volume 26 Issue 14 |
| بيانات النشر: | MDPI, 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Pharmaceutical Science, Infrared spectroscopy, chemistry.chemical_element, chelate, Crystal structure, 010402 general chemistry, 010403 inorganic & nuclear chemistry, 01 natural sciences, Article, Analytical Chemistry, non-covalent interaction, QD241-441, Drug Discovery, Molecule, Non-covalent interactions, Physical and Theoretical Chemistry, X-ray crystallography, chemistry.chemical_classification, Quantitative Biology::Biomolecules, Chemistry, Hydrogen bond, Organic Chemistry, palladium, hydrogen bonding, 0104 chemical sciences, Crystallography, Molecular geometry, Chemistry (miscellaneous), Proton NMR, Molecular Medicine, amino acid, Palladium |
| الوصف: | The reaction of palladium(II) acetate with acyclic amino acids in acetone/water yields square planar bis-chelated palladium amino acid complexes that exhibit interesting non-covalent interactions. In all cases, complexes were examined by multiple spectroscopic techniques, especially HRMS (high resolution mass spectrometry), IR (infrared spectroscopy), and 1H NMR (nuclear magnetic resonance) spectroscopy. In some cases, suitable crystals for single crystal X-ray diffraction were able to be grown and the molecular structure was obtained. The molecular geometries of the products are discussed. Except for the alanine complex, all complexes incorporate water molecules into the extended lattice and exhibit N-H···O and/or O···(HOH)···O hydrogen bonding interactions. The non-covalent interactions are discussed in terms of the extended lattice structures exhibited by the structures. Published version |
| وصف الملف: | application/pdf |
| اللغة: | English |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc5d26f219df0a3fd9433d83e7f79731Test https://hdl.handle.net/10919/104377Test |
| حقوق: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....bc5d26f219df0a3fd9433d83e7f79731 |
| قاعدة البيانات: | OpenAIRE |
| الوصف غير متاح. |