Functional Layers for ZnII Ion Detection: From Molecular Design to Optical Fiber Sensors
| العنوان: | Functional Layers for ZnII Ion Detection: From Molecular Design to Optical Fiber Sensors |
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| المؤلفون: | Radu A. Gropeanu, Klaus Müllen, David Beljonne, Zhihong Liu, Chen Li, Glauco Battagliarin, Mathieu Surin, Roberto Lazzaroni, Claire Tonnelé, Tanja Weil, Marc Debliquy, Jean-Michel Renoirt |
| المصدر: | The Journal of Physical Chemistry B. 118:309-314 |
| بيانات النشر: | American Chemical Society (ACS), 2013. |
| سنة النشر: | 2013 |
| مصطلحات موضوعية: | Ions, Aqueous solution, Molecular Structure, Inorganic chemistry, Isothermal titration calorimetry, Imides, Surfaces, Coatings and Films, Ion, Zinc, chemistry.chemical_compound, chemistry, Materials Chemistry, Proton NMR, Fiber Optic Technology, Physical and Theoretical Chemistry, Spectroscopy, Selectivity, Perylene, Derivative (chemistry) |
| الوصف: | We report on the synthesis of a novel perylene monoimide derivative that shows high response and selectivity for zinc ion detection. The complexation of Zn(2+) by the dye is followed by FD-MS, (1)H NMR, UV-vis spectroscopy, and isothermal titration calorimetry. Quantum chemical calculations are performed to gain further insight into the electronic processes responsible for the spectroscopic changes observed upon complexation. Finally, the perylene dye is incorporated in a sol-gel silica layer coated on optical fibers that are then used for Zn(2+) detection in aqueous solution. |
| تدمد: | 1520-5207 1520-6106 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::32b97d514c1d42daae50580e2074e2c0Test https://doi.org/10.1021/jp407460cTest |
| رقم الانضمام: | edsair.doi.dedup.....32b97d514c1d42daae50580e2074e2c0 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15205207 15206106 |
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