Water as DES-cosolvent on the morphology tuning and photochromic enhancement of tungsten oxide-molybdenum oxide nanocomposite

التفاصيل البيبلوغرافية
العنوان: Water as DES-cosolvent on the morphology tuning and photochromic enhancement of tungsten oxide-molybdenum oxide nanocomposite
المؤلفون: Fang Yao, Olayinka Oderinde, Yuanfeng Wu, Ismaeel Adebayo, Mengmeng Kang, Guodong Fu, Kalulu Mulenga, Imtiaz Hussain
المصدر: Journal of Industrial and Engineering Chemistry. 80:1-10
بيانات النشر: Elsevier BV, 2019.
سنة النشر: 2019
مصطلحات موضوعية: Materials science, Nanocomposite, General Chemical Engineering, Oxide, chemistry.chemical_element, 02 engineering and technology, Tungsten, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, Deep eutectic solvent, chemistry.chemical_compound, chemistry, Chemical engineering, X-ray photoelectron spectroscopy, Molybdenum, Crystallite, Fourier transform infrared spectroscopy, 0210 nano-technology
الوصف: In this study, we report the utilization of different water contents (0–40 vol.%) as cosolvent to ethaline, ChCl:EG (deep eutectic solvent) at the mole ratio of 1:2 to prepare binary oxide of tungsten oxide-molybdenum oxide nanocomposite in an ambient environment, followed by characterization using XRD, FTIR, SEM, TEM, TGA, XPS and UV–vis spectroscopy. The as-prepared composite composed of aggregated particles at low temperature of 60 °C, in the crystallite sizes ranging from ˜48.40 to 71.97 nm, with water cosolvent acting as bad solvent. Further characterizations revealed that the atomic percentage ratios of tungsten and molybdenum components increase with decrease in carbon content as the water content increases, while the morphology changes from cubic to prismatic polyhedral-like structures at low temperature, in addition to retaining ˜73% of its original weight above 700 °C. The UV–vis analysis revealed broad absorption at 239–374 nm with a threshold value of 527 nm and can attain maximum photochromic response in less 60 s on exposure to UV–vis light irradiation.
تدمد: 1226-086X
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_________::f067bfb465ef11d6fe3ff554318656fcTest
https://doi.org/10.1016/j.jiec.2019.07.023Test
حقوق: CLOSED
رقم الانضمام: edsair.doi...........f067bfb465ef11d6fe3ff554318656fc
قاعدة البيانات: OpenAIRE