Kinetics of CH2OO and syn-CH3CHOO reaction with acrolein
| العنوان: | Kinetics of CH2OO and syn-CH3CHOO reaction with acrolein |
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| المؤلفون: | Xueming Yang, Yang Chen, Yiqiang Liu, Xiaohu Zhou, Wenrui Dong, Xinyong Li |
| المصدر: | Physical Chemistry Chemical Physics. 23:13276-13283 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Arrhenius equation, Chemistry, Kinetics, Acrolein, Analytical chemistry, General Physics and Astronomy, 02 engineering and technology, Activation energy, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Aldehyde, 0104 chemical sciences, Reaction rate, chemistry.chemical_compound, symbols.namesake, Torr, symbols, Flash photolysis, Physical and Theoretical Chemistry, 0210 nano-technology |
| الوصف: | The kinetics for the reactions of CH2OO and syn-CH3CHOO with acrolein, a typical unsaturated aldehyde in the atmosphere, were studied in a flash photolysis flow reactor using the OH laser-induced fluorescence (LIF) method. The bimolecular reaction rate coefficients were measured at temperatures ranging from 281 to 318 K, and pressures ranging from 5 to 200 Torr. No obvious dependence of the rate coefficients on pressure was observed under the current experimental conditions. Both reactions exhibit negative temperature-dependence, with an activation energy of (−1.70 ± 0.19) and (−1.47 ± 0.24) kcal mol−1 for CH2OO and syn-CH3CHOO reacting with acrolein, derived from the Arrhenius equation. At 298 K, the measured rate coefficients for CH2OO/syn-CH3CHOO + acrolein reactions are (1.63 ± 0.19) × 10−12 cm3 s−1 and (1.17 ± 0.16) × 10−13 cm3 s−1, respectively. The rate coefficient of the former reaction is in reasonable agreement with a recent theoretical result. |
| تدمد: | 1463-9084 1463-9076 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::e40b339462f6eec8b618ebf44d38d397Test https://doi.org/10.1039/d1cp00492aTest |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi...........e40b339462f6eec8b618ebf44d38d397 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14639084 14639076 |
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