Self-Assembly Behavior and Optical Properties of Poly(3-thiopheneacetate)/Dialkyldimethylammonium Complexes
| العنوان: | Self-Assembly Behavior and Optical Properties of Poly(3-thiopheneacetate)/Dialkyldimethylammonium Complexes |
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| المؤلفون: | Jong-Chan Lee, Kwang-Han Park, Young-Sik Yoon |
| المصدر: | Macromolecular Chemistry and Physics. 210:1510-1518 |
| بيانات النشر: | Wiley, 2009. |
| سنة النشر: | 2009 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Photoluminescence, Polymers and Plastics, Organic Chemistry, urologic and male genital diseases, Condensed Matter Physics, body regions, chemistry.chemical_compound, chemistry, Liquid crystal, Bromide, Phase (matter), Polymer chemistry, otorhinolaryngologic diseases, Materials Chemistry, Thiophene, lipids (amino acids, peptides, and proteins), sense organs, Self-assembly, Physical and Theoretical Chemistry, Absorption (chemistry), Alkyl |
| الوصف: | Poly(3-thiopheneacetate)/dialkyldimethylammonium complexes (PTA-Cn) were prepared by mixing regiorandom poly(3-thiopheneacetic acid) with dialkyldimethylammonium bromide to study the effect of their self-assembled structures on the optical properties. The lengths of the alkyl groups in the ammonium salts were varied from decyl (C10) to octadecyl (C18) groups. These complexes showed fully developed layer structures with ordered mesophases. PTA-C16 and PTA-C18 with longer alkyl groups showed side-chain crystalline phases, and PTA-C10, PTA-C12, and PTA-C14 with shorter alkyl groups showed side-chain crystalline and liquid crystalline phases at room temperature. When PTA-C18 was heated, a melting transition from side-chain crystalline to smectic liquid crystalline phase was observed at 41.5 °C. The maximum absorption and emission wavelengths of these complexes increased with increasing alkyl chain length indicating that the π-conjugated structure of the regiorandom thiophene backbone changes according to the alkyl groups. |
| تدمد: | 1521-3935 1022-1352 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::c618b7ab1107656c1df2871d0201dc8eTest https://doi.org/10.1002/macp.200900109Test |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi...........c618b7ab1107656c1df2871d0201dc8e |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15213935 10221352 |
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