دورية
Two Dieneplatinum Synthetic Reagents, Pt(C6H2F3‐2,4,6)2(cod) and Pt(C6HF4‐2,3,4,5)2(cod)
| العنوان: | Two Dieneplatinum Synthetic Reagents, Pt(C6H2F3‐2,4,6)2(cod) and Pt(C6HF4‐2,3,4,5)2(cod) |
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| المؤلفون: | Deacon, Glen B., Drago, Penny R., Göbbels, Dirk, Junk, Peter C., Meyer, Gerd |
| المصدر: | Zeitschrift für anorganische und allgemeine Chemie; January 2002, Vol. 628 Issue: 1 p167-170, 4p |
| مستخلص: | Reactions of PtCl2(cod) (cod = cycloocta‐1,5‐diene) with 2,4,6‐trifluoro‐ and 2,3,4,5‐tetrafluoro‐phenyllithium in diethyl ether gives Pt(C6H2F3‐2,4,6)2(cod) (1) (monoclinic, P21/n, Z= 4, a= 7.141(1), b= 15.002(2), c= 17.071(3) Å, β = 91.37(2)°) and Pt(C6HF4‐2,3,4,5)2(cod) (2) (triclinic, P 1, Z= 2, a= 10.150(2), b= 10.762(2), c= 10.812(2) Å, α = 63.606(3), β = 63.327(3), γ = 76.496(3)°) respectively, which have two ipso carbon atoms and two double bond midpoint centres in a square planar arrangement, and aromatic rings angled near perpendicular to the coordination plane. |
| قاعدة البيانات: | Supplemental Index |
| تدمد: | 00442313 15213749 |
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| DOI: | 10.1002/1521-3749(200201)628:1<167::AID-ZAAC167>3.0.CO;2-0 |