التفاصيل البيبلوغرافية
| العنوان: |
Kinetic, structural and electrostatic aspects of the reduction of pentacyanoferrate(III) complexes by myoglobin. |
| المؤلفون: |
Ilkowska, Elwira, Lewiński, Krzysztof, van Eldik, Rudi, Stochel, Grażyna |
| المصدر: |
Journal of Biological Inorganic Chemistry (JBIC); Jul1999, Vol. 4 Issue 3, p302-310, 9p |
| مستخلص: |
The mechanism of the reduction of pentacyanoferrate(III) complexes by oxymyoglobin has been studied by conventional and high-pressure kinetic methods, and also by structural modelling. The results of this and an earlier study show that an outer-sphere mechanism is operating for electron transfer between oxymyoglobin and FeIII(CN)5L n –, independent of the lability of the ligand L. The electron transfer process is preceded by precursor formation at a specific site on the protein close to the protein heme pocket. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
