دورية أكاديمية

Electrochemical sensing of phenolic pollutant catechol on LaNiO3 perovskite nanostructure platform.

التفاصيل البيبلوغرافية
العنوان: Electrochemical sensing of phenolic pollutant catechol on LaNiO3 perovskite nanostructure platform.
المؤلفون: Krishnamoorthy, Kaveri, Sivaraman, Narmatha, Sudha, Velayutham, Senthil Kumar, Sakkarapalayam Murugesan, Thangamuthu, Rangasamy
المصدر: Journal of Applied Electrochemistry; Jul2024, Vol. 54 Issue 7, p1637-1645, 9p
مصطلحات موضوعية: CATECHOL, X-ray photoelectron spectroscopy, POLLUTANTS, PEROVSKITE, ELECTROCHEMICAL sensors, TRANSMISSION electron microscopy
مستخلص: Facile synthesis of perovskite materials for the electrochemical sensing applications are remains challenging. In the current work, a simplified electrochemical sensor system based on an electrode modifier containing LaNiO3 was developed to detect catechol (CC). The surface micrograph of LaNiO3 was examined using X-ray diffraction pattern (XRD), X-ray photoelectron spectroscopy (XPS), and High-resolution transmission electron microscopy (HRTEM). Besides, the LaNiO3 reveals a remarkable electrooxidation response for the detection of catechol by cyclic voltammetry (CV) and amperometry techniques. The suggested sensor platform shows a broad linear range for catechol detection from 5 µM to 2000 µM with LOD and sensitivity of 0.6 µM and 54 µA cm−2 mM−1, respectively, under optimised conditions. Furthermore, LaNiO3 altered GCE was fruitfully implemented for the quantification of catechol in tap water sample. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:0021891X
DOI:10.1007/s10800-023-02055-y