دورية أكاديمية

Analyzing the photoassociation spectrum of ultracold 85Rb 133Cs molecule in (3)3Σ+ state.

التفاصيل البيبلوغرافية
العنوان: Analyzing the photoassociation spectrum of ultracold 85Rb 133Cs molecule in (3)3Σ+ state.
المؤلفون: Wang, Zi-wei, Li, Zi-ang, Bai, Xu-hui, Gong, Ting, Ji, Zhong-hua, Zhao, Yan-ting, Wang, Gao-ren
المصدر: Journal of Chemical Physics; 3/21/2024, Vol. 160 Issue 11, p1-9, 9p
مستخلص: We establish a theoretical model to analyze the photoassociative spectroscopy of 85Rb 133Cs molecules in the (3)3Σ+ state. The vibrational energy, spin–spin coupling constant, and hyperfine interaction constant of the (3)3Σ+ state are determined based on nine observed vibrational levels. Consequently, the Rydberg–Klein–Rees potential energy curve of the (3)3Σ+ state is obtained and compared with the ab initial potential energy curve. Our model can be adopted to analyze the photoassociative spectroscopy of other heteronuclear alkali-metal diatomic molecules in the (3)3Σ+ state. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:00219606
DOI:10.1063/5.0182907