دورية أكاديمية

Advance in reversible Zn anodes promoted by 2D materials.

التفاصيل البيبلوغرافية
العنوان: Advance in reversible Zn anodes promoted by 2D materials.
المؤلفون: Lei, Shu-Yuan, Feng, Jin-Xiu, Chen, Yu-Chao, Zheng, Dong, Liu, Wen-Xian, Shi, Wen-Hui, Wu, Fang-Fang, Cao, Xie-Hong
المصدر: Rare Metals; Apr2024, Vol. 43 Issue 4, p1350-1369, 20p
الملخص (بالإنجليزية): With the growing energy demand associated with high safety and low-cost requirement, aqueous zinc-ion batteries (AZIBs) have been considered as one of the most promising next-generation batteries. However, some key issues, such as uncontrollable dendrites growth, severe corrosion, hydrogen evolution and side reactions of Zn anodes during charge/discharge process, have hindered its pragmatic applications. Two-dimensional (2D) materials hold advantages of unique physical and chemical properties, large surface areas and abundant active sites, which have been successfully used to overcome the above shortcomings of Zn anodes in recent years. In this review, the issues and challenges of Zn anodes are outlined. Then, the state-of-the-art progress on Zn anodes modification based on 2D materials such as graphene, 2D metal carbides and nitrides (MXenes), 2D metal-organic frameworks (MOFs), 2D covalent organic frameworks (COFs), 2D transition metal compounds and other 2D materials is discussed in detail. Finally, the perspectives of employing 2D materials in highly reversible Zn anodes are summarized and discussed. [ABSTRACT FROM AUTHOR]
Abstract (Chinese): 摘要: 随着社会对高安全性和低成本能源的需求不断增长,水系锌离子电池(AZIBs)被认为是最有前途的新一代能源电池之一。然而,锌负极在充放电过程中会发生不可控的枝晶生长、严重的腐蚀/析氢和副反应等一些棘手问题,这些问题已经阻碍了锌负极的的实际应用。二维(2D)材料具有以下优点:独特的二维结构、大的比表面积和丰富的活性位点等,近年来已成功应用于锌负极保护,解决锌负极的上述缺陷。在本文中,对锌负极的问题和挑战进行了全面的总结和讨论。然后,详细讨论了石墨烯、2D金属碳化物和氮化物(MXenes)、2D金属有机框架材料(2D MOFs)、2D共价有机框架材料(2D COFs)、2D过渡金属化合物和其他二维纳米材料用于锌负极改性开发的最新进展。在本文的最后,总结和讨论了二维材料用于高可逆锌负极的挑战和前景。 [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:10010521
DOI:10.1007/s12598-023-02478-8