دورية أكاديمية

Synthesis, structural analysis, and photophysical properties of bi-1,2,3-triazoles.

التفاصيل البيبلوغرافية
العنوان: Synthesis, structural analysis, and photophysical properties of bi-1,2,3-triazoles.
المؤلفون: Santana-Martínez, Ivette, Ramírez-Palma, María Teresa, Sánchez-Escalera, Javier, Martínez-Otero, Diego, García-Eleno, Marco A., Dorazco-González, Alejandro, Cuevas-Yañez, Erick
المصدر: Structural Chemistry; Feb2020, Vol. 31 Issue 1, p191-201, 11p
مصطلحات موضوعية: DIHEDRAL angles, PHENYL group, X-ray crystallography, PHOTOLUMINESCENCE, CRYSTAL structure, DIPYRRINS
مستخلص: Structural insights of a group of bi-1,2,3-triazoles derived from oxidative CuAAC are described through an X-ray crystallography study, distinguishing a dihedral angle which is ranged from 76.45 to 86.39° between the two 1,2,3-triazole rings. In addition, compound 1 containing a phenyl moiety displays a strong blue emission (λem = 394 nm); this structure-related photoluminescence is attributed to the rigidity of the molecule and the conjugation between phenyl groups and the triazole fragments. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:10400400
DOI:10.1007/s11224-019-01390-1