التفاصيل البيبلوغرافية
| العنوان: |
Transmission of Unidirectional Molecular Motor Rotation to a Remote Biaryl Axis. |
| المؤلفون: |
Uhl, Edgar, Thumser, Stefan, Mayer, Peter, Dube, Henry |
| المصدر: |
Angewandte Chemie International Edition; 8/20/2018, Vol. 57 Issue 34, p11064-11068, 5p |
| مصطلحات موضوعية: |
MOLECULAR motor proteins, ETHYLENE glycol, X-ray crystallography technique, PHOTOCHEMISTRY, PHYSICAL & theoretical chemistry |
| مستخلص: |
Abstract: Molecular motors undergo repetitive directional motions upon external energy input. A profound challenge is the defined transfer of directional motor motions to remote entities at the molecular scale. Herein, we present a molecular setup that allows for the transfer of the directional rotation of a light‐powered motor unit onto a remote biaryl axis via an ethylene glycol chain link. Based on a combination of X‐ray crystallographic analysis, ECD, and NMR experiments as well as a comprehensive theoretical assessment, we provide evidence for the coupled stepwise directional motions of both molecular units. With the presented setup, facile integration of molecular motor units into larger functional frameworks and complex molecular machines can be explored consciously in the future. [ABSTRACT FROM AUTHOR] |
|
Copyright of Angewandte Chemie International Edition is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
