التفاصيل البيبلوغرافية
| العنوان: |
Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complexElectronic supplementary information (ESI) available: Fig. S1–S5, Table S1, IR spectra at room temperature, and X-ray crystallographic data. CCDC 675170. For crystallographic data in CIF or other electronic format see DOI: 10.1039/b801171k |
| المؤلفون: |
Bao Li1, Jun Tao1, Hao-Ling Sun2, Osamu Sato2, Rong-Bin Huang1, Lan-Sun Zheng1 |
| المصدر: |
Chemical Communications. May2008, Vol. 2008 Issue 19, p2269-2271. 3p. |
| مصطلحات موضوعية: |
*LIGANDS (Chemistry), *CHARGE exchange, *TAUTOMERISM, *COMPLEX compounds synthesis, *INFRARED spectra, *COBALT compounds, *METAL complexes, *X-ray diffraction |
| مستخلص: |
A cobalt complex [{Co(dpqa)}2(dhbq)](PF6)3(1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
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