التفاصيل البيبلوغرافية
| العنوان: |
The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes. |
| المؤلفون: |
Bao Li1, Feng-Lei Yang1, Jun Tao1, Osamu Sato2, Rong-Bin Huang1, Lan-Sun Zheng1 |
| المصدر: |
Chemical Communications. Nov2008, Vol. 2008 Issue 45, p6019-6021. 3p. |
| مصطلحات موضوعية: |
*COBALT compounds, *METAL complexes, *TAUTOMERISM, *VALENCE fluctuations, *MAGNETIC susceptibility, *PRESSURE |
| مستخلص: |
The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)]·(PF6)3(I·(PF6)3) and [{Co(dpqa)}2(dhbq)]·(PF6)3(II·(PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
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