التفاصيل البيبلوغرافية
| العنوان: |
Putting forward a Ni-metallosalphen-based porous organic polymer for detoxification of sulfur mustard gas simulant. |
| المؤلفون: |
Kalita, Priyanka1 (AUTHOR), Paul, Ratul1,2 (AUTHOR), Pao, Chih-Wen3 (AUTHOR), Chatterjee, Rupak4 (AUTHOR), Bhaumik, Asim4 (AUTHOR), Mondal, John1,2 (AUTHOR) johncuchem@gmail.com |
| المصدر: |
Chemical Communications. 4/30/2023, Vol. 59 Issue 34, p5067-5070. 4p. |
| مصطلحات موضوعية: |
*MUSTARD gas, *POROUS polymers, *X-ray absorption, *X-ray spectroscopy, *ISOMERS, *DECONTAMINATION of food |
| مستخلص: |
We have introduced a Friedel–Crafts alkylation strategy of a Ni-salphen complex as derived from 2-hydroxy-5-methoxybenzaldehyde, an isomer of biomass derived vanillin, to construct a Ni-salphen based porous organic polymer (Ni@T-POP). The X-ray absorption spectroscopy (XAS) analysis revealed the existence of Ni–N2O2 core sites in the Ni@T-POP framework, which demonstrates unprecedented catalytic efficiency towards oxidative decontamination of sulfur mustards (HD's) compared to its complex precursor. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
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