دورية أكاديمية
Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability
العنوان: | Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability |
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المؤلفون: | Aldridge, Simon, Caise, Alexa, Crumpton, Agamemnon E., Vasko, Petra, Hicks, Jamie, McManus, Caitilín, Rees, Nicholas H. |
بيانات النشر: | Wiley |
سنة النشر: | 2022 |
المجموعة: | JYX - Jyväskylä University Digital Archive / Jyväskylän yliopiston julkaisuarkisto |
مصطلحات موضوعية: | tin, oxidative addition, reductive elimination, hemi-labile ligand, reversibility, ligandit, tina, orgaaniset tinayhdisteet, kemiallinen synteesi, kompleksiyhdisteet |
الوصف: | We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition. ; peerReviewed |
نوع الوثيقة: | article in journal/newspaper |
وصف الملف: | application/pdf; fulltext |
اللغة: | English |
تدمد: | 1433-7851 |
العلاقة: | Angewandte Chemie; 61; 314794; Research Council of Finland; Suomen Akatemia; Aldridge, S., Caise, A., Crumpton, A. E., Vasko, P., Hicks, J., McManus, C., & Rees, N. H. (2022). Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability. Angewandte Chemie , 61 (5), Article e202114926. https://doi.org/10.1002/anie.202114926Test; CONVID_101984985; URN:NBN:fi:jyu-202111295822; http://urn.fi/URN:NBN:fi:jyu-202111295822Test |
الإتاحة: | http://urn.fi/URN:NBN:fi:jyu-202111295822Test |
حقوق: | In Copyright ; © 2021 Wiley-VCH GmbH ; openAccess ; http://rightsstatements.org/page/InC/1.0/?language=enTest |
رقم الانضمام: | edsbas.AE547B2E |
قاعدة البيانات: | BASE |
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