دورية أكاديمية
Self-Assembled, Millimeter-Sized TIPS-Pentacene Spherulites Grown on Partially Crosslinked Polymer Gate Dielectric
العنوان: | Self-Assembled, Millimeter-Sized TIPS-Pentacene Spherulites Grown on Partially Crosslinked Polymer Gate Dielectric |
---|---|
المؤلفون: | Yoo, Hocheon, Choi, Hyun Ho, Shin, Tae Joo, Rim, Taiuk, Cho, Kilwon, Jung, Sungjune, Kim, Jae-Joon |
بيانات النشر: | WILEY-V C H VERLAG GMBH |
سنة النشر: | 2015 |
المجموعة: | ScholarWorks@UNIST (Ulsan National Institute of Science and Technology) |
الوصف: | Here, a highly crystalline and self-assembled 6,13-bis(triisopropylsilyleth ynyl) pentacene (TIPS-Pentacene) thin films formed by simple spin-coating for the fabrication of high-performance solution-processed organic field-effect transistors (OFETs) are reported. Rather than using semiconducting organic small-molecule-insulating polymer blends for an active layer of an organic transistor, TIPS-Pentacene organic semiconductor is separately self-assembled on partially crosslinked poly-4-vinylphenol:poly(melamine-co-formaldehyde) (PVP:PMF) gate dielectric, which results in a vertically segregated semiconductor-dielectric film with millimeter-sized spherulite-crystalline morphology of TIPS-Pentacene. The structural and electrical properties of TIPS-Pentacene/PVP:PMF films have been studied using a combination of polarized optical microscopy, atomic force microscopy, 2D-grazing incidence wide-angle X-ray scattering, and secondary ion mass spectrometry. It is finally demonstrated a high-performance OFETs with a maximum hole mobility of 3.40 cm(2) V-1 s(-1) which is, to the best of our knowledge, one of the highest mobility values for TIPS-Pentacene OFETs fabricated using a conventional solution process. It is expected that this new deposition method would be applicable to other small molecular semiconductor-curable polymer gate dielectric systems for high-performance organic electronic applications ; close ; 0 ; 0 |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | unknown |
تدمد: | 1616-301X |
العلاقة: | ADVANCED FUNCTIONAL MATERIALS, v.25, no.24, pp.3658 - 3665; https://scholarworks.unist.ac.kr/handle/201301/17053Test; 2765; 24023; 2-s2.0-85027950358; 000356822200005 |
DOI: | 10.1002/adfm.201501381 |
DOI: | 10.1002/adfm.201501381/abstract;jsessionid=A1E6796BFB0C963A455CABE92C86D9AB.f01t04 |
الإتاحة: | https://doi.org/10.1002/adfm.201501381Test https://scholarworks.unist.ac.kr/handle/201301/17053Test |
رقم الانضمام: | edsbas.39644BF3 |
قاعدة البيانات: | BASE |
ResultId |
1 |
---|---|
Header |
edsbas BASE edsbas.39644BF3 792 3 Academic Journal academicJournal 792.1474609375 |
PLink |
https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&scope=site&db=edsbas&AN=edsbas.39644BF3&custid=s6537998&authtype=sso |
FullText |
Array
(
[Availability] => 0
)
Array ( [0] => Array ( [Url] => https://doi.org/10.1002/adfm.201501381# [Name] => EDS - BASE [Category] => fullText [Text] => View record in BASE [MouseOverText] => View record in BASE ) ) |
Items |
Array
(
[Name] => Title
[Label] => Title
[Group] => Ti
[Data] => Self-Assembled, Millimeter-Sized TIPS-Pentacene Spherulites Grown on Partially Crosslinked Polymer Gate Dielectric
)
Array ( [Name] => Author [Label] => Authors [Group] => Au [Data] => <searchLink fieldCode="AR" term="%22Yoo%2C+Hocheon%22">Yoo, Hocheon</searchLink><br /><searchLink fieldCode="AR" term="%22Choi%2C+Hyun+Ho%22">Choi, Hyun Ho</searchLink><br /><searchLink fieldCode="AR" term="%22Shin%2C+Tae+Joo%22">Shin, Tae Joo</searchLink><br /><searchLink fieldCode="AR" term="%22Rim%2C+Taiuk%22">Rim, Taiuk</searchLink><br /><searchLink fieldCode="AR" term="%22Cho%2C+Kilwon%22">Cho, Kilwon</searchLink><br /><searchLink fieldCode="AR" term="%22Jung%2C+Sungjune%22">Jung, Sungjune</searchLink><br /><searchLink fieldCode="AR" term="%22Kim%2C+Jae-Joon%22">Kim, Jae-Joon</searchLink> ) Array ( [Name] => Publisher [Label] => Publisher Information [Group] => PubInfo [Data] => WILEY-V C H VERLAG GMBH ) Array ( [Name] => DatePubCY [Label] => Publication Year [Group] => Date [Data] => 2015 ) Array ( [Name] => Subset [Label] => Collection [Group] => HoldingsInfo [Data] => ScholarWorks@UNIST (Ulsan National Institute of Science and Technology) ) Array ( [Name] => Abstract [Label] => Description [Group] => Ab [Data] => Here, a highly crystalline and self-assembled 6,13-bis(triisopropylsilyleth ynyl) pentacene (TIPS-Pentacene) thin films formed by simple spin-coating for the fabrication of high-performance solution-processed organic field-effect transistors (OFETs) are reported. Rather than using semiconducting organic small-molecule-insulating polymer blends for an active layer of an organic transistor, TIPS-Pentacene organic semiconductor is separately self-assembled on partially crosslinked poly-4-vinylphenol:poly(melamine-co-formaldehyde) (PVP:PMF) gate dielectric, which results in a vertically segregated semiconductor-dielectric film with millimeter-sized spherulite-crystalline morphology of TIPS-Pentacene. The structural and electrical properties of TIPS-Pentacene/PVP:PMF films have been studied using a combination of polarized optical microscopy, atomic force microscopy, 2D-grazing incidence wide-angle X-ray scattering, and secondary ion mass spectrometry. It is finally demonstrated a high-performance OFETs with a maximum hole mobility of 3.40 cm(2) V-1 s(-1) which is, to the best of our knowledge, one of the highest mobility values for TIPS-Pentacene OFETs fabricated using a conventional solution process. It is expected that this new deposition method would be applicable to other small molecular semiconductor-curable polymer gate dielectric systems for high-performance organic electronic applications ; close ; 0 ; 0 ) Array ( [Name] => TypeDocument [Label] => Document Type [Group] => TypDoc [Data] => article in journal/newspaper ) Array ( [Name] => Language [Label] => Language [Group] => Lang [Data] => unknown ) Array ( [Name] => ISSN [Label] => ISSN [Group] => ISSN [Data] => 1616-301X ) Array ( [Name] => NoteTitleSource [Label] => Relation [Group] => SrcInfo [Data] => ADVANCED FUNCTIONAL MATERIALS, v.25, no.24, pp.3658 - 3665; https://scholarworks.unist.ac.kr/handle/201301/17053; 2765; 24023; 2-s2.0-85027950358; 000356822200005 ) Array ( [Name] => DOI [Label] => DOI [Group] => ID [Data] => 10.1002/adfm.201501381 ) Array ( [Name] => DOI [Label] => DOI [Group] => ID [Data] => 10.1002/adfm.201501381/abstract;jsessionid=A1E6796BFB0C963A455CABE92C86D9AB.f01t04 ) Array ( [Name] => URL [Label] => Availability [Group] => URL [Data] => https://doi.org/10.1002/adfm.201501381<br />https://scholarworks.unist.ac.kr/handle/201301/17053 ) Array ( [Name] => AN [Label] => Accession Number [Group] => ID [Data] => edsbas.39644BF3 ) |
RecordInfo |
Array
(
[BibEntity] => Array
(
[Identifiers] => Array
(
[0] => Array
(
[Type] => doi
[Value] => 10.1002/adfm.201501381
)
)
[Languages] => Array
(
[0] => Array
(
[Text] => unknown
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Self-Assembled, Millimeter-Sized TIPS-Pentacene Spherulites Grown on Partially Crosslinked Polymer Gate Dielectric
[Type] => main
)
)
)
[BibRelationships] => Array
(
[HasContributorRelationships] => Array
(
[0] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Yoo, Hocheon
)
)
)
[1] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Choi, Hyun Ho
)
)
)
[2] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Shin, Tae Joo
)
)
)
[3] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Rim, Taiuk
)
)
)
[4] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Cho, Kilwon
)
)
)
[5] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Jung, Sungjune
)
)
)
[6] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Kim, Jae-Joon
)
)
)
)
[IsPartOfRelationships] => Array
(
[0] => Array
(
[BibEntity] => Array
(
[Dates] => Array
(
[0] => Array
(
[D] => 01
[M] => 01
[Type] => published
[Y] => 2015
)
)
[Identifiers] => Array
(
[0] => Array
(
[Type] => issn-print
[Value] => 1616301X
)
[1] => Array
(
[Type] => issn-locals
[Value] => edsbas
)
)
)
)
)
)
)
|
IllustrationInfo |