Biomimetic cooperative interactions of dried cross-linked poly(N-6-aminohexylacrylamide) with binary mixtures of solvent vapors
| العنوان: | Biomimetic cooperative interactions of dried cross-linked poly(N-6-aminohexylacrylamide) with binary mixtures of solvent vapors |
|---|---|
| المؤلفون: | Boris N. Solomonov, Wolf D. Habicher, Valery V. Gorbatchuk, Nikolay A. Mironov |
| المصدر: | Biomacromolecules. 5(4) |
| سنة النشر: | 2004 |
| مصطلحات موضوعية: | Acetonitriles, genetic structures, Polymers and Plastics, Cyclohexane, Chemical Phenomena, Polymers, Inorganic chemistry, Bioengineering, Cooperativity, Biomaterials, Dioxanes, chemistry.chemical_compound, Biomimetics, Materials Chemistry, Organic chemistry, Desiccation, Benzene, Acetonitrile, chemistry.chemical_classification, Acrylamides, Ethanol, Chemistry, Physical, Temperature, Water, Sorption, Polymer, Solvent, Cross-Linking Reagents, chemistry, Solvents, Adsorption, Volatilization, Ternary operation |
| الوصف: | Biomimetic cooperativity of hydration effect and effect of ethanol favorable for binding of bad organic sorbates were observed for their vapor sorption by cross-linked poly(N-6-aminohexylacrylamide) (PNAHAA) in the absence of liquid phase. The vapor sorption isotherms were determined for these systems by the static method of gas chromatographic headspace analysis at 298 K. The hydration above 0.09-0.13 g of H(2)O/(g of polymer) gives a cooperative increase in the PNAHAA binding affinity for benzene, cyclohexane, dioxane, and propanols up to a level which does not change by further hydration, indicating the polymer antiplasticization. Bad sorbates (dioxane, benzene) were observed to have a biomimetic cooperative influence on the binding of ethanol by the dried PNAHAA. This cooperativity does not occur in ternary systems with good nonhydroxylic sorbate acetonitrile. |
| تدمد: | 1525-7797 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4ed6c7b806245b0a427021985d792d20Test https://pubmed.ncbi.nlm.nih.gov/15244486Test |
| رقم الانضمام: | edsair.doi.dedup.....4ed6c7b806245b0a427021985d792d20 |
| قاعدة البيانات: | OpenAIRE |
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