Triaryl-substituted pyrrolo-p-phenylene-linked porphyrin-fullerene dyads: Expanding the structural diversity of photoactive materials
| العنوان: | Triaryl-substituted pyrrolo-p-phenylene-linked porphyrin-fullerene dyads: Expanding the structural diversity of photoactive materials |
|---|---|
| المؤلفون: | Alexander S. Konev, Dmitriy V. Androsov, Kaoru Yamanouchi, Alexey Povolotskiy, Daniil A. Lukyanov, Artem A. Strelnikov, Alexander F. Khlebnikov |
| المصدر: | Tetrahedron. 74:3007-3019 |
| بيانات النشر: | Elsevier BV, 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | Fullerene, 010405 organic chemistry, Organic Chemistry, Aziridine, 010402 general chemistry, Ring (chemistry), 01 natural sciences, Biochemistry, Combinatorial chemistry, Porphyrin, Cycloaddition, 0104 chemical sciences, chemistry.chemical_compound, chemistry, Phenylene, Drug Discovery, Linker, Pyrrole |
| الوصف: | A protocol for the synthesis of pyrrolo-p-phenylene-linked porphyrin-fullerene dyads suitable as photoactive materials was developed. The sequence of aziridination – aziridine ring opening – 1,3-dipolar cycloaddition reactions enabled us to provide structural variability both to the porphyrin core and to pyrrole linker, which facilitates designing the electronic structure and morphological parameters of the dyads. The key porphyrin building blocks, nitro-porphyrins, were synthesized by a stochastic cyclocondensation of arenecarbaldehydes with p-nitrophenyl(dipyrrolyl)methane. |
| تدمد: | 0040-4020 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::907dbf71672d208f5375eaf94b130d9dTest https://doi.org/10.1016/j.tet.2018.04.084Test |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi...........907dbf71672d208f5375eaf94b130d9d |
| قاعدة البيانات: | OpenAIRE |
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