دورية أكاديمية

2,6-Di-tert-butylphenols and phenoxyl radicals with metal—metal bonds.

التفاصيل البيبلوغرافية
العنوان: 2,6-Di-tert-butylphenols and phenoxyl radicals with metal—metal bonds.
المؤلفون: Milaeva, E., Shpakovsky, D., Shaposhnikova, E., Grigor"ev, E., Berberova, N., Egorov, M.
المصدر: Russian Chemical Bulletin; Apr2001, Vol. 50 Issue 4, p716-719, 4p
مستخلص: σ-Aryl trans-bistriphenylphosphine complexes based on 2,6-di- tert-butylphenol containing Pt—SnCl3, Pt—GeCl3 groups were synthesized. Oxidation of these compounds gives the corresponding phenoxyl radicals, which were studied by ESR spectroscopy. The transformation of the diamagnetic complexes to the paramagnetic state is accompanied by cleavage of the Pt—Sn, Pt—Ge bonds and by elimination of SnCl2, GeCl2. [ABSTRACT FROM AUTHOR]
Copyright of Russian Chemical Bulletin is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
قاعدة البيانات: Complementary Index
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Array ( [Name] => Abstract [Label] => Abstract [Group] => Ab [Data] => σ-Aryl trans-bistriphenylphosphine complexes based on 2,6-di- tert-butylphenol containing Pt—SnCl<subscript>3</subscript>, Pt—GeCl<subscript>3</subscript> groups were synthesized. Oxidation of these compounds gives the corresponding phenoxyl radicals, which were studied by ESR spectroscopy. The transformation of the diamagnetic complexes to the paramagnetic state is accompanied by cleavage of the Pt—Sn, Pt—Ge bonds and by elimination of SnCl<subscript>2</subscript>, GeCl<subscript>2</subscript>. [ABSTRACT FROM AUTHOR] )
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