دورية أكاديمية
Investigating the Competitive Factors of Metal–Anion Coordination, Coordination by Water, and Hydrogen Bonding in Complexes of Cyanuric Acid with the Alkaline Earth Metals.
العنوان: | Investigating the Competitive Factors of Metal–Anion Coordination, Coordination by Water, and Hydrogen Bonding in Complexes of Cyanuric Acid with the Alkaline Earth Metals. |
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المؤلفون: | Clegg, William, Nichol, Gary S. |
المصدر: | Crystals (2073-4352); Jan2024, Vol. 14 Issue 1, p98, 20p |
مصطلحات موضوعية: | ALKALINE earth metals, CYANURIC acid, HYDROGEN bonding, X-ray crystallography, METAL ions, AQUEOUS solutions |
مستخلص: | A survey of the trends in metal–ligand coordination and hydrogen bonding has been carried out on complexes of singly deprotonated cyanuric acid CY− and alkaline earth metals, synthesised from aqueous solution and characterised by X-ray crystallography. The involvement of cyanurate in metal coordination increases from Mg through Ca and Sr to Ba relative to coordination by water, in parallel with increasing ionic radius and coordination number. The incidence of the bridging of metal centres by both water and cyanurate also increases in this series. The Mg complex [Mg(H |
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قاعدة البيانات: | Complementary Index |