دورية أكاديمية
Sulfination of Unactivated Allylic Alcohols via Sulfinate–Sulfone Rearrangement
| العنوان: | Sulfination of Unactivated Allylic Alcohols via Sulfinate–Sulfone Rearrangement |
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| المؤلفون: | Yan Wang, Guangming Wu, Kaiyu Yan, Jiaheng Qin, Rui Liu, Nannan Rong, Yongming Tang, Teck-Peng Loh, Peizhong Xie |
| سنة النشر: | 2023 |
| مصطلحات موضوعية: | Biochemistry, Microbiology, Pharmacology, Biotechnology, Computational Biology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, unactivated allylic alcohols, synthetic toolbox, sulfinic acids, study expands, free conditions, excellent yields, dehydrative cross |
| الوصف: | A dehydrative cross-coupling of unactivated allylic alcohols with sulfinic acids was achieved under catalyst-free conditions. This reaction proceeded via allyl sulfination and concomitant allyl sulfinate–sulfone rearrangement. Various allylic sulfones could be obtained in good to excellent yields with water as the only byproduct. This study expands the synthetic toolbox for constructing allylic sulfone molecules. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| العلاقة: | https://figshare.com/articles/journal_contribution/Sulfination_of_Unactivated_Allylic_Alcohols_via_Sulfinate_Sulfone_Rearrangement/24763845Test |
| DOI: | 10.1021/acs.orglett.3c03709.s001 |
| الإتاحة: | https://doi.org/10.1021/acs.orglett.3c03709.s001Test https://figshare.com/articles/journal_contribution/Sulfination_of_Unactivated_Allylic_Alcohols_via_Sulfinate_Sulfone_Rearrangement/24763845Test |
| حقوق: | CC BY-NC 4.0 |
| رقم الانضمام: | edsbas.E66F8F31 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1021/acs.orglett.3c03709.s001 |
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