دورية أكاديمية
Contactless Scanning Near‐Field Optical Dilatometry Imaging at the Nanoscale
| العنوان: | Contactless Scanning Near‐Field Optical Dilatometry Imaging at the Nanoscale |
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| المؤلفون: | Victor Wong, Sabastine Ezugwu, Giovanni Fanchini |
| المصدر: | Advanced Materials Interfaces, Vol 11, Iss 12, Pp n/a-n/a (2024) |
| بيانات النشر: | Wiley-VCH, 2024. |
| سنة النشر: | 2024 |
| المجموعة: | LCC:Physics LCC:Technology |
| مصطلحات موضوعية: | nanogranular materials, scanning‐near field optical microscopy (SNOM), thermal expansion coefficient, thermoreflecance, Physics, QC1-999, Technology |
| الوصف: | Abstract To date, there are very few experimental techniques, if any, that are suitable for the purpose of acquiring quantitative maps of the thermal expansivity of 2D materials and nanostructured thin films with nanoscale lateral resolution in spite of huge demand for nanoscale thermal management, for example in designing integrated circuitry for power electronics. Besides, contactless analytical tools for determining the thermal expansion coefficient (TEC) are highly desirable because probes in contact with the sample significantly perturb any thermal measurements. Here, ω‐2ω near‐field thermoreflectance imaging is presented as a novel, all‐optical, and contactless technique to map the TEC at the nanoscale with precision. Testing of this technique is performed on nanogranular films of gold and multilayer graphene (ML‐G) platelets. With ω‐2ω near‐field thermoreflectance, it is demonstrated that the TEC of Au is higher at the metal‐insulator interface, with an average of (17.12 ± 2.30) ×10−6 K−1 in agreement with macroscopic techniques. For ML‐G, the average TEC is (−5.77 ± 3.79) x10−6 K−1 and is assigned to in‐plane vibrational bending modes. A vibrational‐thermal transition from graphene to graphite is observed, where the TEC becomes positive as the ML thickness increases. The nanoscale method here reported demonstrates results in excellent agreement with its macroscopic counterparts, as well as superior capabilities to probe 2D materials and interfaces. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2196-7350 |
| العلاقة: | https://doaj.org/toc/2196-7350Test |
| DOI: | 10.1002/admi.202300806 |
| الوصول الحر: | https://doaj.org/article/32ffbdd0bb1b476b8b097eed6669f3adTest |
| رقم الانضمام: | edsdoj.32ffbdd0bb1b476b8b097eed6669f3ad |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 21967350 |
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| DOI: | 10.1002/admi.202300806 |